N,N-Diallylamine
Diallylamine
CAS: 124-02-7
Molecular Formula: C6H11N
N,N-Diallylamine - Names and Identifiers
| Name | Diallylamine |
| Synonyms | dillylamine Diallylamine diallyl-amin N,N-Diallylamine Di-2-propenylamine DI-2-PROPENYLAMINE N,N-Di(2-propenyl)amine N-allylprop-2-en-1-amine n-2-propenyl-2-propen-1-amin 2-Propen-1-amine,N-2-propenyl- N-prop-2-en-1-ylprop-2-en-1-amine N-prop-2-en-1-ylprop-2-en-1-aminium |
| CAS | 124-02-7 |
| EINECS | 204-671-2 |
| InChI | InChI=1/C6H11N/c1-3-5-7-6-4-2/h3-4,7H,1-2,5-6H2 |
N,N-Diallylamine - Physico-chemical Properties
| Molecular Formula | C6H11N |
| Molar Mass | 97.16 |
| Density | 0.787 g/mL at 25 °C (lit.) |
| Melting Point | -88 °C (lit.) |
| Boling Point | 111-112 °C (lit.) |
| Flash Point | 60°F |
| Water Solubility | 8.6 g/100mL |
| Solubility | 86g/l |
| Vapor Presure | 18 mm Hg ( 20 °C) |
| Vapor Density | 3.35 (vs air) |
| Appearance | Liquid |
| Color | Clear colorless to yellow |
| Merck | 14,2971 |
| BRN | 773718 |
| pKa | pK1:9.29(+1) (25°C,μ=0.02) |
| PH | 11.5 (9.7g/l, H2O) |
| Storage Condition | Store below +30°C. |
| Sensitive | Air Sensitive |
| Explosive Limit | 0.93-14.2%(V) |
| Refractive Index | n20/D 1.440(lit.) |
| Physical and Chemical Properties | Colorless liquid. Freezing point -100 ℃, boiling point 112 ℃, relative density 0.7889(20 ℃), refractive index 1.4404. Soluble in water, alcohol, ether, benzene, ammonia odor. |
| Use | Used as raw materials for organic synthesis, ionic water purification agent, polymer monomer, pharmaceutical intermediates |
N,N-Diallylamine - Risk and Safety
| Risk Codes | R11 - Highly Flammable R20/22 - Harmful by inhalation and if swallowed. R24 - Toxic in contact with skin R34 - Causes burns |
| Safety Description | S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S28A - |
| UN IDs | UN 2359 3/PG 2 |
| WGK Germany | 3 |
| RTECS | UC6650000 |
| FLUKA BRAND F CODES | 2-10 |
| TSCA | Yes |
| HS Code | 2921 19 99 |
| Hazard Class | 3 |
| Packing Group | II |
| Toxicity | LD50 orally in rats: 0.65 g/kg (Smyth) |
N,N-Diallylamine - Reference Information
| LogP | -0.653 at 23℃ |
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Use | organic intermediates. used as raw materials for organic synthesis, ionic water purification agent, polymer monomer, pharmaceutical intermediates, etc. used as organic synthesis, polymer monomer |
| production method | is obtained by hydrolysis of diallylcyanamide. The hydrolysis reaction was carried out in sulfuric acid medium, and the reflux was relieved for 6H. Yield 80-88%. |
| category | flammable liquid |
| toxicity grade | high toxicity |
| Acute toxicity | oral-rat LD50: 578 mg/kg; Oral-mouse LD50: 355 mg/kg |
| stimulation data | Skin-rabbit 100 μg/24 h; eye-rabbit 50 mg/20 s severe |
| flammability hazard characteristics | in case of fire, high temperature, oxidant flammable; toxic NOx smoke from combustion |
| storage and transportation characteristics | The warehouse is ventilated and dried at low temperature; Stored separately from oxidants and acids |
| extinguishing agent | dry powder, dry sand, carbon dioxide, foam, 1211 extinguishing agent |
| Occupational Standard | sel 1 mg/m3 |
| spontaneous combustion temperature | 273°C |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-09 20:48:19
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