Name | [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride |
Synonyms | Pd(R-BINAP)Cl2 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYLPALLAD ((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium [(S)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride [(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE [(R)-(+)-2,2'-Bis(Diphenylphosphino)-1,1'-Binaphthyl]Palladium(Ii) Chloride Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II),(R-BINAP)PdCl2 Palladium,[1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]dichloro-, (SP-4-2)- |
CAS | 115826-95-4 |
EINECS | 621-611-4 |
InChI | InChI=1/C44H32P2.2ClH.Pd/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;/h1-32H;2*1H;/q;;;+2/p-2 |
Molecular Formula | C44H32Cl2P2Pd |
Molar Mass | 800 |
Melting Point | 106-108 ℃(lit.) |
Boling Point | 724.3°C at 760 mmHg |
Flash Point | 419°C |
Vapor Presure | 5.55E-20mmHg at 25°C |
Appearance | Orange powder or block |
Storage Condition | under inert gas (nitrogen or Argon) at 2–8 °C |
Sensitive | Moisture Sensitive |
MDL | MFCD00075254 |
Hazard Symbols | Xn - Harmful |
Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 - Wear suitable gloves and eye/face protection |
WGK Germany | 3 |
Use | [(R)-( )-2,2 '-bis (diphenylphosphine)-1,1'-binaphthalene] Palladium dichloride is an organometallic derivative, which can be used as a precious metal catalyst. |