Propenylmagnesiumbromide - Names and Identifiers
Propenylmagnesiumbromide - Physico-chemical Properties
Molecular Formula | C3H5BrMg
|
Molar Mass | 145.28 |
Density | 0.95g/mLat 25°C |
Boling Point | 65°C |
Flash Point | −4°F |
Vapor Presure | 8480mmHg at 25°C |
Appearance | Solution |
Color | Light yellow to orange to brown |
Storage Condition | 2-8°C |
Propenylmagnesiumbromide - Risk and Safety
Risk Codes | R11 - Highly Flammable
R14/15 -
R19 - May form explosive peroxides
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R34 - Causes burns
R37 - Irritating to the respiratory system
R40 - Limited evidence of a carcinogenic effect
R36/37/38 - Irritating to eyes, respiratory system and skin.
R15 - Contact with water liberates extremely flammable gases
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Safety Description | S16 - Keep away from sources of ignition.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27 - Take off immediately all contaminated clothing.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S36/37 - Wear suitable protective clothing and gloves.
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UN IDs | UN 3399 4.3/PG 1 |
WGK Germany | 3 |
HS Code | 29319090 |
Propenylmagnesiumbromide - Introduction
1-propyl magnesium bromide is an organic compound with the chemical formula C3H7MgBr. The following is a description of its nature, use, preparation and safety information:
Nature:
-Appearance: 1-propylmagnesium bromide is a colorless to pale yellow liquid.
-Solubility: Soluble in ether, ethanol and dimethylformamide, insoluble in water.
-Melting point: approximately at -50°C.
-Boiling point: Under normal pressure, its boiling point is about 110°C.
Use:
- 1-propyl magnesium bromide is commonly used as a reagent in organic synthesis.
-It can be used as an alkylation reagent in organic synthesis, and is often used to introduce propyl groups.
-It can also be used as a catalyst to promote the reaction of certain organic compounds.
Preparation Method:
-1-propylmagnesium bromide is generally obtained by reacting ethyl bromide with metallic magnesium. The reaction conditions can be carried out in the presence of a drying agent, such as a drying agent 4Å molecular sieve, and the reaction temperature is usually from room temperature to 35°C.
-The reaction equation is as follows: C3H7Br Mg → C3H7MgBr.
Safety Information:
- 1-propyl magnesium bromide is dangerous, is an organic compound. Contact with skin, eyes or inhalation of its vapors may cause irritation.
-use should wear protective glasses, gloves, protective clothing and other personal protective equipment.
-Pay attention to a well-ventilated environment during operation and avoid inhaling its vapor.
-In case of skin or eye contact, rinse immediately with plenty of water and seek medical assistance.
-Store 1-propylmagnesium bromide in a dry, ventilated place away from sources of ignition or heat.
Last Update:2024-04-10 22:29:15