SODIUMBROMATE,CRYSTAL,REAGENT
Sodium bromate
CAS: 7789-38-0
Molecular Formula: BrNaO3
SODIUMBROMATE,CRYSTAL,REAGENT - Names and Identifiers
| Name | Sodium bromate |
| Synonyms | UN1494 Dyetone dyetone HSDB 2185 NSC 77383 CCRIS 9265 Sodium bromate bromatedesodium Neutralizer K-126 Bromate de sodium Neutralizer K-938 Neutralizer K-140 SodiumBromateNaBrO3 Sodium bromate(DOT) SODIUM BROMATE REAGENT bromatedesodium[french] Sodium bromate (NaBrO3) Bromic acid, sodium salt Bromate de sodium [French] SODIUMBROMATE,CRYSTAL,REAGENT Sodium bromate [UN1494] [Oxidizer] |
| CAS | 7789-38-0 |
| EINECS | 232-160-4 |
| InChI | InChI=1/BrHO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 |
| InChIKey | XUXNAKZDHHEHPC-UHFFFAOYSA-M |
SODIUMBROMATE,CRYSTAL,REAGENT - Physico-chemical Properties
| Molecular Formula | BrNaO3 |
| Molar Mass | 150.89 |
| Density | 3.339 g/mL at 25 °C (lit.) |
| Melting Point | 755°C(lit.) |
| Boling Point | 1390 °C |
| Water Solubility | 364 g/L (20 ºC) |
| Solubility | H2O: 1M at20°C, clear, colorless |
| Vapor Presure | 1 mm Hg ( 806 °C) |
| Appearance | Powder/Solid |
| Specific Gravity | 3.34 |
| Color | White |
| Merck | 14,8593 |
| PH | 5.0-9.0 (25℃, 50mg/mL in H2O) |
| Storage Condition | Store below +30°C. |
| Stability | Stable. Oxidizer. Incompatible with finely powdered metals, alcohols, strong acids, strong reducing agents. |
| Refractive Index | 1.594 |
| Physical and Chemical Properties | White or colorless cubic crystalline or crystalline particles. Melting Point: 381 ℃ relative density: 3.339(17.5 ℃) solubility: soluble in water, solubility: 27.5g/100ml water at 0 ℃, the solubility at 100 °c is 90.9g/of water. Insoluble in alcohol. |
| Use | Printing and Dyeing auxiliaries, daily chemicals in the Perm agent, chemical reagents, cleaning agents |
SODIUMBROMATE,CRYSTAL,REAGENT - Risk and Safety
| Risk Codes | R8 - Contact with combustible material may cause fire R22 - Harmful if swallowed R36/37/38 - Irritating to eyes, respiratory system and skin. R9 - Explosive when mixed with combustible material R36/37 - Irritating to eyes and respiratory system. |
| Safety Description | S17 - Keep away from combustible material. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S37/39 - Wear suitable gloves and eye/face protection |
| UN IDs | UN 1494 5.1/PG 2 |
| WGK Germany | 3 |
| RTECS | VZ3150000 |
| FLUKA BRAND F CODES | 3 |
| TSCA | Yes |
| HS Code | 2829 90 40 |
| Hazard Note | Oxidising Agent/Harmful |
| Hazard Class | 5.1 |
| Packing Group | II |
| Toxicity | LD50 orally in Rabbit: 400 mg/kg |
SODIUMBROMATE,CRYSTAL,REAGENT - Upstream Downstream Industry
| Raw Materials | Sodium hydroxide Bromine |
| Downstream Products | Potassium bromate 3-Bromoanisole |
SODIUMBROMATE,CRYSTAL,REAGENT - Nature
Open Data Verified Data
white or colorless cubic crystals or crystalline particles. Relative density 3. 339 (17.5 deg C), the melting point of 381 deg C, soluble in water, 0 deg C solubility of 27. 5g/lOOmL water, 100 deg C when the solubility is 90. 9g/lOOmL water, insoluble in alcohol. The solid decomposes when heated at high temperature. This strain is strong oxidant, flammable; And organic compounds, sulfides and other mixed grinding flammable, easy to explosion, and sulfuric acid contact easy to fire or explosion. Storage and transport of articles is specified for storage and transport.
Last Update：2024-01-02 23:10:35
SODIUMBROMATE,CRYSTAL,REAGENT - Preparation Method
Open Data Verified Data
chlorine oxidation method: first, the reaction is carried out by adding bromine Dropwise to lime milk prepared by lime powder and water to generate Calcium bromate and calcium bromide, and then chlorine gas is introduced for oxidation reaction. The filtrate was filtered, washed, and concentrated. The reaction is carried out by adding barium chloride solution at low temperature, and the Barium bromate produced by the reaction is washed with water and then metathesized with sodium carbonate, and then filtered, evaporated, crystallized, separated and dried to obtain a sodium bromate finished product.
Last Update：2022-01-01 10:59:25
SODIUMBROMATE,CRYSTAL,REAGENT - Use
Open Data Verified Data
mainly used for the preparation of inorganic chemical products, chemical reagents for the determination of phenols, also commonly used as oxidants, laboratory bromine generator, cosmetics cold perm agent; Industrial used as wool finishing agent, it is also used for the extraction and purification of precious and heavy metals.
Last Update：2022-01-01 10:59:24
SODIUMBROMATE,CRYSTAL,REAGENT - Safety
Open Data Verified Data
packed with large-mouth iron (Wood) barrels lined with two-layer polyethylene plastic bags, each with a net weight of 40kgI inside and outside the packages have obvious "toxic"_explosive "_strong oxidant" identification; should be stored in a dry, cool, well-ventilated warehouse, should be away from ammonium compounds and sulfuric acid, not with flammable and explosive materials, storage and transportation, to prevent rain and sun exposure, when loading and unloading should be light to prevent packaging damage. It is a strong oxidant. Risk code: GB Class 5.1 515100 UN N0.1494; IMDG Code page 5178, Class 3. When there is a fire, it can be suppressed by sand and various kinds of fire extinguisher. Ingestion or inhalation of this product will appear vertigo, Nausea, Vomit, if any, immediately consult a doctor; To avoid eye, skin contact with this product, if contact, rinse immediately with fresh water and ask a doctor for treatment.
Last Update：2022-01-01 10:59:26
SODIUMBROMATE,CRYSTAL,REAGENT - Reference Information
| pH range of acid-base indicator discoloration | 5 - 9 |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| solubility in water (g/100ml) | grams dissolved per 100ml of water at different temperatures (℃): 24.2g/0 ℃;30.3g/10 ℃;36.4g/20 ℃;42.6g/30 ℃;48.8g/40 ℃; 62.6g/60 ℃;75.7g/80 ℃;90.8g/100 ℃ |
| toxicity | if you ingest or inhale this product, you will experience dizziness, Nausea, Vomit. To avoid eye, skin contact with this product, if contact, immediately rinse with fresh water, and ask a doctor for treatment. |
| Use | used as oxidant, Perm agent, wool finishing agent, also used for extraction and purification of precious metals mainly used for the preparation of inorganic chemical products, chemical reagents for the determination of phenols. It is also commonly used as an oxidant, a laboratory bromine generator, and a cosmetic cold perm agent. It is used as wool finishing agent in industry, and also used for extraction and purification of precious and heavy metals. for Capacity Analysis, can also be used as an oxidant for Capacity Analysis, can also be used as an oxidant printing and dyeing auxiliaries, daily chemicals in the Perm agent, chemical reagents, cleaning agent |
| production method | The chlorine oxidation method first reacts by adding bromine Dropwise to lime milk prepared by lime powder and water to generate Calcium bromate and calcium bromide, then chlorine gas was introduced for oxidation reaction. The filtrate was filtered, washed, and concentrated. The reaction is carried out by adding barium chloride solution at low temperature, and the Barium bromate produced by the reaction is washed with water and then metathesized with sodium carbonate, and then filtered, evaporated, crystallized, separated and dried to obtain a sodium bromate finished product. 6Ca(OH)2 6Br2 → Ca(BrO3)2 5CaBr2 6H2OCaBr2 6C12 6Ca(OH)2 → Ca(BrO3)2 6CaCl2 6 H2OCa(BrO3)2 BaCl2 → Ba(BrO3)2 ↓ CaCl2Ba(BrO3)2 Na2CO3 → 2NaBrO3 BaCO3 ↓ |
| category | oxidant |
| toxicity grade | high toxicity |
| Acute toxicity | intraperitoneal-mouse LD50: 140 mg/kg |
| explosive hazard characteristics | mixed with reductant, sulfur, phosphorus, etc, friction can burst |
| flammability hazard characteristics | toxic bromide and sodium oxide fumes from combustion |
| storage and transportation characteristics | The warehouse is ventilated and dried at low temperature; It is light and easy to discharge; It is combined with organic matter, reductant, sulfur and phosphorus combustible substances, separate storage of food raw materials |
| fire extinguishing agent | water and sand mist |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-09 20:49:11
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View History
SODIUMBROMATE,CRYSTAL,REAGENT
亚铬酸铜催化剂
盐酸土霉素
C10-13ALKYLBENZENESULFONICACID,SODIUMSALT
Sodium D-Glucuronate Monohydrate
Tevilon
Isopropylethylketone
DIMETHYLBENZYLAMINE
ethyl (2Z)-chloro(phenylhydrazono)ethanoate
7757-69-9
亚铬酸铜催化剂
盐酸土霉素
C10-13ALKYLBENZENESULFONICACID,SODIUMSALT
Sodium D-Glucuronate Monohydrate
Tevilon
Isopropylethylketone
DIMETHYLBENZYLAMINE
ethyl (2Z)-chloro(phenylhydrazono)ethanoate
7757-69-9
Raw Materials for SODIUMBROMATE,CRYSTAL,REAGENT
Downstream Products for SODIUMBROMATE,CRYSTAL,REAGENT