Tris(1,2,3,4-tetramethyl-2,4-cyclopentadienyl)cerium(III) - Names and Identifiers
Name | Tris(1,2,3,4-tetramethyl-2,4-cyclopentadienyl)cerium(III)
|
Synonyms | TRIS(TETRAMETHYLCYCLOPENTADIENYL)CERIUM Tris(tetramethylcyclopentadienyl)cerium (III) TRIS(1,2,3,4-TETRAMETHYL-2,4-CYCLOPENTADIENYL)CERIUM(III) Tris(1,2,3,4-tetramethyl-2,4-cyclopentadienyl)cerium(III) TRIS(TETRAMETHYLCYCLOPENTADIENYL)CERIUM, PACKAGED IN AMPULES ON 1 GM
|
CAS | 251984-08-4
|
Tris(1,2,3,4-tetramethyl-2,4-cyclopentadienyl)cerium(III) - Physico-chemical Properties
Molecular Formula | C27H39Ce15*
|
Molar Mass | 503.71 |
Flash Point | 140°F |
Appearance | Powder |
Color | green |
Storage Condition | Flammables area |
Sensitive | Moisture Sensitive |
MDL | MFCD01863662 |
Tris(1,2,3,4-tetramethyl-2,4-cyclopentadienyl)cerium(III) - Risk and Safety
Hazard Symbols | F - Flammable
|
Risk Codes | R11 - Highly Flammable
R14 - Reacts violently with water
|
Safety Description | 16 - Keep away from sources of ignition.
|
UN IDs | UN 1325 4.1/PG 2 |
WGK Germany | 3 |
HS Code | 29310099 |
Hazard Class | 4.1 |
Packing Group | III |
Tris(1,2,3,4-tetramethyl-2,4-cyclopentadienyl)cerium(III) - Introduction
Tris(1,2,3,4-tetramethyl-2,4-cyclopentadienyl)cerium(III) is an organometallic compound with the chemical formula Ce(Cp *)3, where Cp * represents 1,2,3,4-tetramethyl-2,4-cyclopentadienyl (Cp * is an organic ligand). It has the following properties:
1. appearance: usually orange to red solid.
2. Melting point: about 120-130°C.
3. Stability: relatively stable in the air, but gradually hydrolyzed in water.
4. solubility: can be dissolved in organic solvents (such as ether, toluene, dimethylformamide, etc.).
Tris(1,2,3,4-tetramethyl-2,4-cyclopentadienyl)cerium(III) has the following uses:
1. Catalyst: It can be used as a catalyst for organic synthesis reactions, such as carbene reaction, oxidation reaction, etc.
2. electrochemical applications: can be used for the preparation of batteries, electrolytic cells and metal-organic framework compounds.
3. Materials Science: It can be used to synthesize organic-inorganic composite materials, liquid crystal materials and optical materials.
The preparation method usually involves the following steps:
1. First, cerium trichloride (CeCl3) and tetramethylcyclopentadienyl lithium (LiCp *) were reacted in a hydrogen atmosphere to obtain tetramethylcyclopentadienyl cerium (III).
2. Then, the product is purified by steps of recrystallization, solvent extraction, etc.
Last Update:2024-04-10 22:29:15