acetamidinato)dicopper(I)

acetamidinato)dicopper(I) - Names and Identifiers

Name	Bis(N,N'-di-sec-butylacetamidinato)dicopper(I)
Synonyms	Bis(N,N'-di-sec-butyL acetamidinato)dicopper(I) (N,N'-DI-SEC-BUTYLACETAMIDINATO)COPPER(I) Bis(N,N'-di-sec-butylacetamidinato)dicopper(I) BIS(N,N'-DI-SEC-BUTYLACETAMIDINATO)DICOPPER (I) Bis[mu-[N,N'-bis(1-methylpropyl)ethanimidamidato]]dicopper
CAS	695188-31-9

acetamidinato)dicopper(I) - Physico-chemical Properties

Molecular Formula	C20H42Cu2N4
Molar Mass	465.67
Melting Point	77 °C
Appearance	crystal
Color	white to off-white
Storage Condition	-20℃
Sensitive	air sensitive, moisture sensitive, store cold

acetamidinato)dicopper(I) - Introduction

Bis(N,N'-di-sec-butylacetamidinato)dicopper(I) is an organocopper complex with the chemical formula [Cu(NH = C(R)2)2]2. Its properties are as follows:

1. Appearance: Bis(N,N'-di-sec-butylacetamidinato)dicopper(I) is a pale yellow crystalline solid.
2. melting point: its melting point is about 100-105 ℃.
3. Solubility: It is soluble in non-polar solvents such as chloroform, benzene, etc., and almost insoluble in water.
4. Stability: The compound is relatively stable, relatively stable in the air, and slightly reduced in stability under light.

The main uses of Bis(N,N'-di-sec-butylacetamidinato)dicopper(I) are as follows:

1. catalyst: it can be used as a catalyst to participate in a variety of organic synthesis reactions such as C- C bond formation reaction, heptadiene cyclization reaction, alkyne furanization reaction.
2. Chemical vapor deposition: It can be used to prepare metal copper thin films and is suitable for chemical vapor deposition technology.
3. Electrochemical application: The compound has potential application value in the field of electrochemistry, and can be used in dye-sensitized solar cells and other devices.

The preparation of Bis(N,N'-di-sec-butylacetamidinato)dicopper(I) usually proceeds through the following steps:

1. First, dibutylamine reacts with amide in an organic solvent such as chloroform to generate N,N-di-sec-butyl amide.
2. The N,N-di-sec-butylamide is then reacted with a copper(I) salt (e. g. cuprous chloride) under an inert atmosphere to form the Bis(N,N'-di-sec-butylacetamidinato)dicopper(I).

Note the following safety information when using and handling Bis(N,N'-di-sec-butylacetamidinato)dicopper(I):

1. Avoid contact with skin and eyes: This substance can irritate skin and eyes. When in contact, rinse immediately with plenty of water and seek medical help.
2. avoid inhalation and intake: avoid inhalation of its dust or solution vapor, avoid eating. If this happens, medical help should be sought immediately.
3. Maintain a well-ventilated environment: When using this compound, ensure that the operating place is well ventilated to avoid its vapor accumulation.
4. storage and handling: the compound should be stored in a dry, cool place, and away from the fire and oxidant. Waste shall be disposed of in accordance with relevant laws and regulations.

It should be noted that this is only a general description of the compound and safety information, and does not cover all details. Please follow appropriate laboratory practices and safety regulations in specific applications.

Last Update：2024-04-10 22:29:15