Molecular Formula | C10H9NO6S2 |
Molar Mass | 303.31 |
Density | 1.6329 (rough estimate) |
Boling Point | 205.8°C (rough estimate) |
Storage Condition | 2-8°C |
Refractive Index | 1.7330 (estimate) |
Physical and Chemical Properties | Appearance is white powder, insoluble in water. |
Use | Used as sun-resistant, reactive dye intermediates, such as the synthesis of active yellow, active golden yellow, active Brown |
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
Raw Materials | Sulfuric acid Naphthalene Nitric acid |
white crystals. Slightly soluble in water.
naphthalene by sulfonation, nitration, and then separation of isomers and magnesium salt 2 Nitro 4,8 A naphthalene disulfonic acid magnesium salt, adding sodium hydroxide into sodium salt, the product is then reduced with iron powder in hydrochloric acid medium.
dye intermediates.
EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
Overview | The pure product of 2-naphthylamine -4, 8-disulfonic acid is white crystal and soluble in water. Industrial products are bluish fluorescent tan liquid or gray paste. After sulfonation from naphthalene by fuming sulfuric acid and nitrification with mixed acid, the isomer is separated with magnesium salt (MgCO3) to obtain 2-nitro-4, 8-dinaphthalene sulfonate magnesium salt, and sodium hydroxide is added to make it Sodium salt, and then reduced to obtain, which is a dye intermediate. |
application | the commercial name of the product with the chemical name 2-naphthylamine-4,8-disulfonic acid (2-naphthylamine-4,8-disulfonic acid) is amino c acid, which is a reactive dye and a direct dye intermediate. the synthesis process is based on naphthalene as a raw material and sulfonated to form 1,5-naphthylsulfonic acid, 2-nitro -4,8-naphthalene sulfonic acid is generated by nitrification, magnesium oxide is added to the nitrification reaction solution to make it produce 2-nitro -4,8-naphthalene sulfonic acid magnesium salt precipitate, and the filtered filtrate is acidic wastewater. |
use | used as an intermediate for sun-resistant and reactive dyes, such as synthesis of reactive yellow, reactive golden yellow, reactive brown, etc. this product is a dye intermediate for synthesis of reactive dye and direct dyes, such as reactive yellow, reactive golden yellow, reactive brown and direct sun-resistant blue B2BL, etc. |
production method | naphthalene is sulfonated and nitrated, and then the isomers are separated by magnesium salt to obtain 2-nitro-4, 8-dinaphthalene sulfonate magnesium salt, add sodium hydroxide to form sodium salt, and then reduce with iron powder in acidic medium to prepare the finished product. Raw material consumption quota: refined naphthalene 852kg/t, fuming sulfuric acid (containing SO 320%)888kg/t, nitric acid 444kg/t, soda ash 581kg/t, liquid alkali (30%)256kg/t, sulfuric acid (92.5%)73kg/t, iron powder 807kg/t, magnesium carbonate 1615kg/t. |
category | toxic substances |
toxicity classification | low toxicity |
acute toxicity | oral-rat LD50: 11400 mg/kg |
stimulation data | eyes-rabbit 100 mg/24 hours moderate |
flammability hazard characteristics | combustible; combustion produces toxic nitrogen oxides and sulfur oxide smoke |
storage and transportation characteristics | warehouse ventilation and low temperature drying |
fire extinguishing agent | dry powder, foam, sand, carbon dioxide, mist water |