Name | 4-fluorophenylmagnesium bromide |
Synonyms | bromo(4-fluorophenyl)magnesium 4-fluorophenylmagnesium bromide magnesium bromide fluorobenzenide (4-Fluorophenyl)-magnesium bromide (4-fluorophenyl)magnesium(1+) bromide |
CAS | 352-13-6 |
EINECS | 627-087-3 |
InChI | InChI=1/C6H4F.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q;;+1/p-1/rC6H4FMg.BrH/c7-5-1-3-6(8)4-2-5;/h1-4H;1H/q+1;/p-1 |
InChIKey | QYBFFRXNNFXREA-UHFFFAOYSA-M |
Molecular Formula | C6H4BrFMg |
Molar Mass | 199.303 |
Density | 1.043 g/mL at 25 °C |
Melting Point | 5 °C |
Boling Point | 66°C |
Flash Point | −40 °F |
Water Solubility | It reacts violently with water. |
Appearance | Clear yellow to red-brown solution |
Stability | Air & Moisture Sensitive |
Use | 4-Fluorophenylmagnesium bromide is used as a reagent for the introduction of the 4-Fluorophenyl group. |
Risk Codes | R12 - Extremely Flammable R14 - Reacts violently with water R22 - Harmful if swallowed R34 - Causes burns R66 - Repeated exposure may cause skin dryness or cracking R67 - Vapors may cause drowsiness and dizziness R11 - Highly Flammable R40 - Limited evidence of a carcinogenic effect R37 - Irritating to the respiratory system R19 - May form explosive peroxides |
Safety Description | S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S7/8 - S33 - Take precautionary measures against static discharges. S8 - Keep container dry. S7 - Keep container tightly closed. |
UN IDs | UN 2924 3/PG 2 |
WGK Germany | 1 |
FLUKA BRAND F CODES | 10-21 |
TSCA | Yes |
HS Code | 29319090 |
Hazard Class | 3 |
Packing Group | II |
Melting point 5°C
Boiling point 66°C
Density 1.043g/mL at 25 c
Flash point & minus;40 °F
Storage conditions Flammables water-Freezer (-20°C)e area
Morphological Solution
Color Clear yellow to red-brown
Water solubility It reacts violently with water.
Sensitivity Air & Moisture Sensitive
BRN 636802
InChIKey QYBFFRXNNFXREA-UHFFFAOYSA-M
security information
Dangerous goods mark f, c, f
Hazard category code 12-14-22-34-66-67-11-40-37-19
Safety instructions 16-26-36/37/39-43-45-7/8-33-8-7
Dangerous goods transportation number UN 2924 3/PG 2
WGK Germany 1
F 10-21
TSCA Yes
HazardClass 3
PackingGroup II
Customs code 29319090