chloro(tricyclohexyl)stannane
Tricyclohexylchlorotin
CAS: 3091-32-5
Molecular Formula: C18H33ClSn
chloro(tricyclohexyl)stannane - Names and Identifiers
| Name | Tricyclohexylchlorotin |
| Synonyms | Tricyclohexylchlorotin TRICYCLOHEXYLCHLOROTIN CHLOROTRICYCLOHEXYLTIN TRICYCLOHEXYLTIN CHLORIDE Tricyclohexyltin chloride chlorotricyclohexyl-stannan chlorotricyclohexylstannane Tricyclohexylolobic chloride chloro(tricyclohexyl)stannane TRICYCLOHEXYL STANNIC CHLORIDE TRICYCLOHEXYLTIN CHLORIDE, PURIFIED Tricyclohexyltin chloride,Chlorotricyclohexyltin |
| CAS | 3091-32-5 |
| EINECS | 221-437-5 |
| InChI | InChI=1/3C6H11.ClH.Sn/c3*1-2-4-6-5-3-1;;/h3*1H,2-6H2;1H;/q;;;;+1/p-1/rC18H33ClSn/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2 |
chloro(tricyclohexyl)stannane - Physico-chemical Properties
| Molecular Formula | C18H33ClSn |
| Molar Mass | 403.62 |
| Melting Point | 123-125 °C (lit.) |
| Boling Point | >250°C |
| Flash Point | >150°C |
| Water Solubility | Soluble in ethanol, ether, toluene and chloroform. Insoluble in water. |
| Vapor Presure | 1.61E-06mmHg at 25°C |
| Exposure Limit | ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 |
| Storage Condition | 2-8°C |
| Physical and Chemical Properties | Tricyclohexyltin chloride is a white solid, insoluble in water, soluble in xylene. |
chloro(tricyclohexyl)stannane - Risk and Safety
| Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 - After contact with skin, wash immediately with plenty of soap-suds. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S60 - This material and its container must be disposed of as hazardous waste. |
| UN IDs | 3146 |
| WGK Germany | 3 |
| RTECS | WH6830000 |
| TSCA | Yes |
| HS Code | 29319090 |
| Hazard Class | 6.1(b) |
| Packing Group | III |
chloro(tricyclohexyl)stannane - Reference Information
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| Uses | Tricyclohexyl tin chloride is an important intermediate for the synthesis of acaricide tricyclic tin and triadimestine. |
| Production method | Tricyclohexyl tin chloride is made from chlorocyclohexane and tin tetrachloride. In 500 L stainless steel reactor, pre-processed magnesium tablets are added, and a certain amount of mixed solution of chlorocyclohexane and THF is added under the protection of nitrogen. After the reaction is started, continue to add the remaining mixed solution. After the reaction is completed, it reacts with the xylene solution of tin tetrachloride to generate tricyclohexyl tin chloride and magnesium chloride. Add dilute hydrochloric acid to dissolve magnesium chloride, stratify to obtain a xylene solution of tricyclohexyl tin chloride, and remove xylene to obtain a finished product. |
Last Update：2024-04-10 22:29:15
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