chlorodimethyl(phenyl)silane

Name	Chlorodimethylphenylsilane
Synonyms	CP0160 DMPSCl DMPSCI PHENYLDIMETHYLCHLOROSILANE Chlorodimethylphenylsilane CHLORODIMETHYLPHENYLSILANE chlorodimethylphenyl-silan Phenyldimethylchlorosilane Dimethylphenylchlorosilane DIMETHYLPHENYL-CHLOROSILANE DIMETHYLPHENYLSILYLCHLORIDE Dimethylphenylsilyl chloride chlorodimethyl(phenyl)silane Dimethylphenylchlorosilane~Dimethylphenylsilyl chloride~DMPSCl~Phenyldimethylchlorosilane
CAS	768-33-2
EINECS	212-193-0
InChI	InChI=1/C8H11ClSi/c1-10(2,9)8-6-4-3-5-7-8/h3-7H,1-2H3
InChIKey	KWYZNESIGBQHJK-UHFFFAOYSA-N

Molecular Formula	C8H11ClSi
Molar Mass	170.71
Density	1.017g/mLat 25°C(lit.)
Melting Point	<0°C
Boling Point	194-198°C
Flash Point	143°F
Water Solubility	MAY DECOMPOSE
Solubility	Miscible with tetrahydrofuran, ether and hexane.
Vapor Presure	0.572mmHg at 25°C
Appearance	clear liquid
Specific Gravity	1.017
Color	Colorless to Light yellow
BRN	606292
Storage Condition	Inert atmosphere,Room Temperature
Sensitive	Moisture Sensitive
Refractive Index	n20/D 1.509(lit.)
MDL	MFCD00000499
Use	It is used for the synthesis of enantiomeric-enriched bialkylene silanes by the Claisen rearrangement reaction of orthoester of chiral silyl propargyl alcohol.

Hazard Symbols	C - Corrosive
Risk Codes	R34 - Causes burns R37 - Irritating to the respiratory system
Safety Description	S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
UN IDs	UN 2987 8/PG 2
WGK Germany	1
FLUKA BRAND F CODES	10-21
TSCA	Yes
HS Code	29319090
Hazard Class	8
Packing Group	II

NIST chemical information	information provided by: webbook.nist.gov (external link)
EPA chemical substance information	information provided by: ofmpeb.epa.gov (external link)
Introduction	phenyldimethylchlorosilane is a commercially available organic synthon in common organic solvents such as dichloromethane, dimethyl sulfoxide, N,N-dimethylformamide, ethyl acetate and other good solubility. The compound belongs to a kind of chlorosilane, which is often used as a hydroxyl protecting group in organic synthesis.
synthesis method	at 0 °c to dichlorodimethylsilane (1.15 ML, 9.6 mmol) to a solution in Et2O(5 ml) was added dropwise (phenyl) magnesium bromide, which was prepared from 4-bromobenzene (1.0 mL, 9.6 mmol) and magnesium powder particles (0.25g, 10.6 mmol) prepared. The reaction mixture was allowed to warm to room temperature and stirred for 24 hours. After completion of the reaction, pentane was added to the reaction mixture, the resulting precipitate was filtered off, and the volatile substances were evaporated by rotary evaporation, the spin-dried residue was purified by vacuum distillation (85 °c/6 mmHg) to give Chloro (phenyl) dimethylsilane.

Last Update：2024-04-10 22:29:15

Spot supply

Product Name: Chlorodimethylphenylsilane Request for quotation
CAS: 768-33-2
Tel: +86-18162425036
Email: 3866263148@qq.com
Mobile: 18162425036
QQ: 3866263148

Send QQ message
Wechat: 18162425036

Product Name: Chloro(dimethyl)phenylsilane Visit Supplier Webpage Request for quotation
CAS: 768-33-2
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409

Wechat: 18301782025

Spot supply

Product Name: Chlorodimethylphenylsilane Request for quotation
CAS: 768-33-2
Tel: +86-18162425036
Email: 3866263148@qq.com
Mobile: 18162425036
QQ: 3866263148

Send QQ message
Wechat: 18162425036

Product Name: Chloro(dimethyl)phenylsilane Visit Supplier Webpage Request for quotation
CAS: 768-33-2
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409

Wechat: 18301782025

View History

chlorodimethyl(phenyl)silane

chlorodimethyl(phenyl)silane Request for Quotation