chlorophenylmagnesium
chlorophenylmagnesium
CAS: 100-59-4
Molecular Formula: C6H5ClMg
chlorophenylmagnesium - Names and Identifiers
| Name | chlorophenylmagnesium |
| Synonyms | chlorophenylmagnesium Phenylmagnesium chloride |
| CAS | 100-59-4 |
| EINECS | 202-868-8 |
| InChI | InChI=1/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q-1;;+2/p-1 |
| InChIKey | GQONLASZRVFGHI-UHFFFAOYSA-M |
chlorophenylmagnesium - Physico-chemical Properties
| Molecular Formula | C6H5ClMg |
| Molar Mass | 136.862 |
| Density | 0.98 g/mL at 20 °C |
| Melting Point | 89-90℃ |
| Boling Point | 78.8°C at 760 mmHg |
| Flash Point | 1 °F |
| Water Solubility | It reacts violently with water. |
| Vapor Presure | 101mmHg at 25°C |
| Stability | Air & Moisture Sensitive |
| Physical and Chemical Properties | The yellowish brown to dark brown solution has a density of 0.98 g/mL at 20°C. |
| Use | Phenylmagnesium chloride is used in organic synthesis, in particular in the preparation of hydrocarbons, Alcohols, Ketones, organic acids, amines, silicones, boranes. |
chlorophenylmagnesium - Risk and Safety
| Risk Codes | R14 - Reacts violently with water R19 - May form explosive peroxides R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R34 - Causes burns R67 - Vapors may cause drowsiness and dizziness R65 - Harmful: May cause lung damage if swallowed R63 - Possible risk of harm to the unborn child R48 - Danger of serious damage to health by prolonged exposure R11 - Highly Flammable R40 - Limited evidence of a carcinogenic effect R37 - Irritating to the respiratory system |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S62 - If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. S33 - Take precautionary measures against static discharges. S16 - Keep away from sources of ignition. |
| UN IDs | UN 2924 3/PG 2 |
| WGK Germany | 2 |
| FLUKA BRAND F CODES | 10 |
| TSCA | Yes |
| HS Code | 29319090 |
| Hazard Class | 8 |
| Packing Group | II |
| Toxicity | Reacts with water, steam or acids to produce toxic and flammable vapors with evolution of heat. |
chlorophenylmagnesium - Upstream Downstream Industry
chlorophenylmagnesium - Introduction
Phenylmagnesium chloride is an organic compound with the chemical formula of C6H5ClMg. It is an organic magnesium reagent with the following properties:
1. Reactivity: Phenyl magnesium chloride can react with alkyl halides, aldehydes, ketones and other compounds to generate the corresponding substitution products.
2. Solubility: Phenyl magnesium chloride has relatively good solubility and can be reacted in organic solvents.
The main uses of phenyl magnesium chloride include the following aspects:
1. Organic synthesis: As an organic magnesium reagent, phenyl magnesium chloride is commonly used in organic synthesis reactions and can be used to synthesize a variety of organic compounds, such as substituted phenyl, alcohols, aldehydes, ketones, etc.
2. Catalyst: Phenyl magnesium chloride can be used as a catalyst or ligand in metal organic chemical reactions.
the preparation of phenyl magnesium chloride generally has two kinds:
1. direct synthesis: phenyl lithium reacts with magnesium chloride to generate phenyl magnesium chloride.
2. reaction method of magnesium chloride and bromobenzene: the reaction of magnesium chloride and bromobenzene in anhydrous ether to generate phenyl magnesium chloride.
The safety information for phenyl magnesium chloride is as follows:
1. High irritation to skin and eyes, so pay attention to avoid direct contact when using.
2. with flammability, avoid contact with fire or high temperature material.
3. Keep away from fire and oxidant during storage and keep the container sealed.
4. use should wear protective gloves, goggles and other personal protective equipment.
5. During operation, a well-ventilated environment should be ensured.
note: this is only a brief introduction to phenyl magnesium chloride, specific use and operation should also refer to the relevant chemical literature and safety data.
Last Update：2024-04-09 19:55:45
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