cis,cis-bicyclohexyl
bicyclohexyl
CAS: 92-51-3
Molecular Formula: C12H22
cis,cis-bicyclohexyl - Names and Identifiers
| Name | bicyclohexyl |
| Synonyms | bicyclohexyl Dicyclohexane Bicyclohexane 1,1-Bicyclohexyl 1,1'-bicyclohexyl 1,1'-Bicyclohexyl 1,1'-Bi(cyclohexyl) cis,cis-bicyclohexyl Cyclohexylcyclohexane Cyclohexane, cyclohexyl- 1,1'-Biphenyl, dodecahydro- |
| CAS | 92-51-3 |
| EINECS | 202-161-4 |
| InChI | InChI=1/C12H22/c1-3-7-11(8-4-1)12-9-5-2-6-10-12/h11-12H,1-10H2 |
| InChIKey | WVIIMZNLDWSIRH-UHFFFAOYSA-N |
cis,cis-bicyclohexyl - Physico-chemical Properties
| Molecular Formula | C12H22 |
| Molar Mass | 166.3 |
| Density | 0.864g/mLat 25°C(lit.) |
| Melting Point | 3-4°C(lit.) |
| Boling Point | 227°C(lit.) |
| Flash Point | 92 °C |
| Solubility | Difficult to mix. |
| Vapor Presure | 0.0633mmHg at 25°C |
| Appearance | Liquid |
| Specific Gravity | 0.864 |
| Color | Colorless to nearly colorless |
| BRN | 1848266 |
| Storage Condition | Store below +30°C. |
| Stability | Stable. Flammable. Incompatible with strong oxidizing agents. |
| Refractive Index | n20/D 1.478(lit.) |
cis,cis-bicyclohexyl - Risk and Safety
| Risk Codes | R50 - Very Toxic to aquatic organisms R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Safety Description | S23 - Do not breathe vapour. S24/25 - Avoid contact with skin and eyes. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S60 - This material and its container must be disposed of as hazardous waste. |
| UN IDs | UN3082 - class 9 - PG 3 - DOT NA1993 - Environmentally hazardous substances, liquid, n.o.s. HI: all (not BR) |
| WGK Germany | 3 |
| TSCA | T |
| HS Code | 29021990 |
| Hazard Class | IRRITANT |
cis,cis-bicyclohexyl - Reference Information
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Application | bicyclohexane is an organic compound, which can be used for pharmaceutical and chemical intermediates. |
| preparation | a, by catalytic hydrogenation reaction, the boiling point of the impurity 3-cyclohexylcyclohexene contained in the dicyclohexyl ether recovered from the residue of cyclohexanol distillation is 230.4 ℃, the boiling point of 1-cyclohexylcyclohexene is 234.2 °c and the boiling point of cyclohexylidene cyclohexane is 237.6 °c. The boiling point of 1-cyclohexylcyclohexene is 227 °c, the boiling point difference between the impurity compound and dicyclohexyl ether was increased to 242.5 ℃. The reaction temperature of catalytic hydrogenation was 80-220 ℃, the reaction pressure was 1-10 MPa, and the reaction time was 1-6 h, the amount of catalyst is 0.3-10% of the mass ratio of dicyclohexyl ether recovered from cyclohexanol distillation residue, and the stirring speed is 50-600 r/min; B, precise separation of dicyclohexanes and dicyclohexyl ether by vacuum distillation; Separation by batch distillation column, open the vacuum pump, maintain the vacuum of the distillation system 133, gradually heated to 110 ℃, collection of distillation column overhead temperature of 99-100.5 deg C, to obtain the bicyclohexane product, collection of distillation column overhead temperature of 101-102 deg C Fractions to give dicyclohexyl ether product. |
| autoignition temperature | 473 ° F. |
Last Update：2024-04-09 21:21:28
