Name | ETHIOFENCARB |
Synonyms | arylmate chox1901 croneton500 ETHIOFENCARB bay-hox-1901 alpha-ethylthio-o-tolylmethylcarbamate 2-ethyl-mercaptomethyl-phenyl-n-methylcarbamate |
CAS | 29973-13-5 |
EINECS | 249-981-9 |
Molecular Formula | C11H15NO2S |
Molar Mass | 225.31 |
Density | 1.231 g/cm3 (20 ºC) |
Melting Point | 43-45℃ |
Boling Point | 327.3±34.0 °C(Predicted) |
Water Solubility | 1800 mg l-1 (20 °C) |
Vapor Presure | 4.5 x 10-4 Pa (20 °C) |
Appearance | neat |
BRN | 2973224 |
pKa | 12.09±0.46(Predicted) |
Storage Condition | APPROX 4°C |
Refractive Index | 1.4790 (estimate) |
Physical and Chemical Properties | The original drug is a brown-red oily liquid with a relative density of about 1.147(20 ℃) and a vapor pressure of 1.333 × 10-2Pa(30 ℃). At room temperature, the solubility in benzene, toluene, xylene, n-propanol, dichloromethane is> 600g/L, and the solubility in water is 900mg/L (1820mg/L). |
Risk Codes | R22 - Harmful if swallowed R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
Safety Description | S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
UN IDs | 2992 |
WGK Germany | 3 |
RTECS | FC2628000 |
HS Code | 29309090 |
Hazard Class | 6.1(b) |
Packing Group | III |
Toxicity | LC50 (96-hour) for carp 10–20 mg/L, golden orfe 8–10 mg/L, goldfish 20–40 mg/L and rudd 10–20 mg/L (Hartley and Kidd, 1987); acute oral LD50 for rats 411–499 mg/kg (Hartley and Kidd, 1987), 200 mg/kg (RTECS, 1985). |
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
toxicity | The acute oral LD50 in rats was 411 mg/kg (-499mg/kg), rat acute percutaneous LD50>4000mg/kg 91150mg/kg), no irritation to rabbit eyes, rats 90d feeding Test No effect dose of 4.64mg/kg per day. Accumulation coefficient> 5.3, no mutagenic effect under the experimental conditions, no teratogenic effect. |
Use | has the advantages of gastric poison, contact killing and internal absorption, high efficiency, low toxicity and safety. It has special effects on aphids, and can be used to control aphids in wheat and peach trees. To control wheat aphids, at the booting stage of wheat, when the rate of stem reached 30% and the population was above 150, 25% emulsifiable concentrate 1250~1500mL/hm2 (effective component 312.5 ~ 375g) was used. The water 750 ~ 900kg spray, the sustained effect period is 5 ~ 7d, the two medication interval 10d. Control of Myzus persicae with 25% emulsifiable concentrate 500~1000 times liquid spray. methyl ethyl dithiocarbamate is a kind of high efficiency, low toxicity and low residue of systemic carbamate insecticide, which has good control effect on aphids, crustaceans, diamondback moth, cockroaches, mosquitoes and flies, for the control of fruit trees, vegetables, potatoes, sugar beet, tobacco and other crops on the aphids, aphids resistant to organic phosphorus is more effective, with a long residual effect. |
production method | using phenol as raw material, synthesis of intermediate O-ethylthiomethylphenol by one-step pressure method, this is followed by addition with methyl isocyanate to produce ethyl thiomethyl. O-ethylthiomethyl phenol is prepared by the interaction of N-methyl isocyanate. |
category | pesticide |
toxicity grade | high toxicity |
Acute toxicity | oral-rat LD50: 200 mg/kg; Oral-mouse LD50: 71 mg/kg |
flammability hazard characteristics | toxic nitrogen oxide and oxygen sulfide gases from combustion |
storage and transportation characteristics | The warehouse is ventilated and dried at low temperature; It is stored and transported separately from food raw materials |
extinguishing agent | dry powder, foam, sand |
toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |