dodecacarbonyltetra-μ-hydridotetraosmium
DODECACARBONYLTETRA-MU-HYDRIDOTETRAOSMIUM
CAS: 12375-04-1
Molecular Formula: C12O12Os4
dodecacarbonyltetra-μ-hydridotetraosmium - Names and Identifiers
| Name | DODECACARBONYLTETRA-MU-HYDRIDOTETRAOSMIUM |
| Synonyms | powder, dodecacarbonyltetra-μ-hydridotetraosmium Dodecacarbonyltetra-m-hydridotetraOsmium DODECACARBONYLTETRA-MU-HYDRIDOTETRAOSMIUM |
| CAS | 12375-04-1 |
| InChI | InChI=1/12CO.4Os.4H/c12*1-2;;;;;;;;/r2C6H2O6Os2/c2*7-1-13(2-8,3-9)14(4-10,5-11)6-12/h2*13-14H |
dodecacarbonyltetra-μ-hydridotetraosmium - Physico-chemical Properties
| Molecular Formula | C12O12Os4 |
| Molar Mass | 1097.04 |
| Physical and Chemical Properties | WGK Germany:3 |
dodecacarbonyltetra-μ-hydridotetraosmium - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. |
| WGK Germany | 3 |
dodecacarbonyltetra-μ-hydridotetraosmium - Introduction
Dodecarbonyl tetra-μ-osmium hydride (also known as [Os3(CO)10(μ-H)2]) is an inorganic compound with the chemical formula Os3(CO)10(μ-H)2. The following is a summary of the properties, use, preparation and safety information of the compound:
Nature:
-Dodecarbonyl tetra-μ-osmium hydride is a colorless crystal or yellow powder.
-It is insoluble in water, but soluble in organic solvents such as toluene, benzene and chloroform.
-The compound is stable in the air, but may decompose when heated.
-It can be characterized by techniques such as nuclear magnetic resonance and infrared spectroscopy.
Use:
-Dodecarbonyl tetra-μ-osmium hydride can be used as a catalyst. It has potential applications in catalytic hydrogenation of olefins, catalytic addition of CO, catalytic carbonylation and so on. It can also be used as a catalyst for electrochemical synthesis and electrolysis of water to produce hydrogen and other reactions.
-In addition, it also plays a role in the fields of organic synthesis and material chemistry.
Preparation Method:
-Dodecarbonyl tetra-μ-osmium hydride can be prepared by a number of methods, including reduction of tricarbonyl osmium chloride by sodium hydride in acetonitrile, or reaction of osmium chloride with tricarbonyl phosphorus under hydrogen atmosphere at high temperature, etc.
Safety Information:
-Dodecarbonyl tetra-μ-osmium hydride may be harmful to humans and may cause irritation to the skin, eyes and respiratory tract.
-Take appropriate precautions during handling and use, such as wearing protective gloves, safety glasses and breathing apparatus.
-Waste should be disposed of in accordance with local regulations.
-In a laboratory or industrial environment, strict safety procedures should be followed to avoid direct contact and inhalation of the compound.
Nature:
-Dodecarbonyl tetra-μ-osmium hydride is a colorless crystal or yellow powder.
-It is insoluble in water, but soluble in organic solvents such as toluene, benzene and chloroform.
-The compound is stable in the air, but may decompose when heated.
-It can be characterized by techniques such as nuclear magnetic resonance and infrared spectroscopy.
Use:
-Dodecarbonyl tetra-μ-osmium hydride can be used as a catalyst. It has potential applications in catalytic hydrogenation of olefins, catalytic addition of CO, catalytic carbonylation and so on. It can also be used as a catalyst for electrochemical synthesis and electrolysis of water to produce hydrogen and other reactions.
-In addition, it also plays a role in the fields of organic synthesis and material chemistry.
Preparation Method:
-Dodecarbonyl tetra-μ-osmium hydride can be prepared by a number of methods, including reduction of tricarbonyl osmium chloride by sodium hydride in acetonitrile, or reaction of osmium chloride with tricarbonyl phosphorus under hydrogen atmosphere at high temperature, etc.
Safety Information:
-Dodecarbonyl tetra-μ-osmium hydride may be harmful to humans and may cause irritation to the skin, eyes and respiratory tract.
-Take appropriate precautions during handling and use, such as wearing protective gloves, safety glasses and breathing apparatus.
-Waste should be disposed of in accordance with local regulations.
-In a laboratory or industrial environment, strict safety procedures should be followed to avoid direct contact and inhalation of the compound.
Last Update：2024-04-10 22:29:15
