Name | N-Ethylaniline |
Synonyms | Aethylanilin Ethylaniline ethyl aniline anilinoethane n-ethyl-anilin N-Ethylaniline N-EthylaniIine Ethylphenylamine N-ethylanilinium monoethylaniline Aniline, N-ethyl- n-ethyl-benzenamin N-Ethylbenzenamine N-ethyl-Benzenamine N-ethylaminobenzene |
CAS | 103-69-5 |
EINECS | 203-135-5 |
InChI | InChI=1/C8H11N/c1-2-9-8-6-4-3-5-7-8/h3-7,9H,2H2,1H3/p+1 |
Molecular Formula | C8H11N |
Molar Mass | 121.18 |
Density | 0.963g/mLat 25°C(lit.) |
Melting Point | -63 °C |
Boling Point | 205°C(lit.) |
Flash Point | 185°F |
Water Solubility | 50 g/L (20 ºC) |
Solubility | 2.7g/l |
Vapor Presure | 0.2 mm Hg ( 25 °C) |
Vapor Density | 4.2 (vs air) |
Appearance | Liquid |
Color | Clear light yellow to light brown |
Exposure Limit | NIOSH: IDLH 100 ppm |
Merck | 14,3764 |
BRN | 507468 |
pKa | 5.12(at 24℃) |
PH | 11 (2.7g/l, H2O, 20℃) |
Storage Condition | Store below +30°C. |
Stability | Stable, but decomposes upon prolonged exposure to air or light. Combustible. Incompatible with strong oxidizing agents. May react violently with nitric acid. |
Sensitive | Air & Light Sensitive |
Explosive Limit | 1.8-10.0%(V) |
Refractive Index | n20/D 1.554(lit.) |
Physical and Chemical Properties | Colorless liquid. Melting Point -63.5 ℃ (freezing point -80 ℃), boiling point 204.5 ℃,83.8 ℃(1.33kPa), relative density 0.958(25 ℃),0.9625(20 ℃), refractive index 1.5559, flash point 85 C, ignition point 85 C (open). Insoluble in water and ether, soluble in alcohol and most organic solvents. Light or open air is easy to quickly turn brown, aniline odor. |
Use | Used as pesticide and dye intermediates, rubber accelerator, etc |
Hazard Symbols | T - Toxic |
Risk Codes | R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R33 - Danger of cumulative effects |
Safety Description | S28 - After contact with skin, wash immediately with plenty of soap-suds. S37 - Wear suitable gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S28A - |
UN IDs | UN 2272 6.1/PG 3 |
WGK Germany | 1 |
RTECS | BX9780000 |
FLUKA BRAND F CODES | 8 |
TSCA | Yes |
HS Code | 29214200 |
Hazard Note | Toxic |
Hazard Class | 6.1 |
Packing Group | III |
Toxicity | LD50 in rats (g/kg): 0.18 i.p., 0.28 orally, 4.7 s.c. (Sziza, Podhragyai) |
Raw Materials | Aniline Ethyl Alcohol |
Downstream Products | 2-(N-Ethylanilino)ethanol 1,3-diethyl-1,3-diphenylurea |
colorless liquid. Melting Point -63.5 °c. Boiling point 204.5 degrees C, 83 degrees C (1.33kPa). Relative density 0. 958 (25 ℃),0.9625 (20 ℃). Refractive index 5559, flash point 85 °c. Ignition point 85 degrees C (open). Insoluble in water and ether, soluble in alcohol and most organic solvents. It quickly turns brown when exposed to sunlight or air.
This product is used in organic synthesis and is an important intermediate of azo dyes and triphenylmethane dyes. It can also be used in the production of rubber additives and other fine chemical products.
This product is toxic. LD50 334mg/kg. The toxicity was similar to that of aniline, but slightly weaker. Can cause methemoglobinemia, cause tissue hypoxia, damage to the central nervous system and other organs. For protection, packaging, storage and transportation, see 2, 6-methylaniline (C 247).
LogP | 2.26 at 25℃ and pH6-8 |
NIST chemical information | information provided by: webbook.nist.gov (external link) |
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
Use | This product is used in organic synthesis, is an important intermediate for azo dyes and triphenylmethane dyes; Can also be used for rubber additives, intermediates of fine chemicals such as explosives and photographic materials. used as pesticide and dye intermediates, rubber accelerator, etc. organic synthesis. Dye Intermediates. |
production method | 1. Hydrochloric acid aniline hydrochloride and ethanol at 180 ℃, 2.94MPa reaction, distillation of excess ethanol and by-product ether, then add 30% NaOH and p-Toluenesulfonyl chloride, with steam distillation to remove the by-product diethylaniline, the product can be obtained by adding sulfuric acid. 2. Phosphorus trichloride aniline, ethanol and phosphorus trichloride were reacted at 300 ° C. And 9.84MPa, and the reaction mixture was fractionated by vacuum distillation to obtain N-ethylaniline. |
category | toxic substances |
toxicity grade | poisoning |
Acute toxicity | inhalation-rat LC50: 1130 mg/m3/4 h |
flammability hazard characteristics | high thermal decomposition, flammable; toxic nitrogen oxides and hydrogen chloride fumes from combustion |
storage and transportation characteristics | The warehouse is ventilated and dried at low temperature, separate storage of food additives |
fire extinguishing agent | foam, carbon dioxide, sand, dry powder |
toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |