phenyl-lithiu
phenyllithium
CAS: 591-51-5
Molecular Formula: C6H5Li
phenyl-lithiu - Names and Identifiers
| Name | phenyllithium |
| Synonyms | PHLI phenyllithium phenyl-lithiu Phenyllithium PHENYLLITHIUM Lithium, phenyl- lithium benzenide PHENYLLITHIUM DIBUTYL Phenyllithium solution, 1.9M in di-n-butyl ether PhenyllithiuM, 1.0 M solution in ethyl ether, SpcSeal PhenyllithiuM, 2.0 M solution in dibutyl ether, SpcSeal |
| CAS | 591-51-5 |
| EINECS | 209-720-1 |
| InChI | InChI=1/C6H5.Li/c1-2-4-6-5-3-1;/h1-5H;/rC6H5Li/c7-6-4-2-1-3-5-6/h1-5H |
| InChIKey | NHKJPPKXDNZFBJ-UHFFFAOYSA-N |
phenyl-lithiu - Physico-chemical Properties
| Molecular Formula | C6H5Li |
| Molar Mass | 84.05 |
| Density | 0.835g/mLat 25°C |
| Melting Point | 160-163 °C(Solv: benzene (71-43-2)) |
| Boling Point | 140-143 °C |
| Flash Point | 20 °C |
| Water Solubility | Severe reaction |
| Solubility | Miscible with ether and hydrocarbons. |
| Appearance | Dark Brown Solution |
| BRN | 506502 |
| Storage Condition | Store at +2°C to +8°C. |
| Stability | Moisture Sensitive |
| Sensitive | Air & Moisture Sensitive |
phenyl-lithiu - Risk and Safety
| Risk Codes | R11 - Highly Flammable R14 - Reacts violently with water R17 - Spontaneously flammable in air R34 - Causes burns R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 - Vapors may cause drowsiness and dizziness R66 - Repeated exposure may cause skin dryness or cracking R65 - Harmful: May cause lung damage if swallowed R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R22 - Harmful if swallowed R19 - May form explosive peroxides R35 - Causes severe burns R36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S62 - If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. S60 - This material and its container must be disposed of as hazardous waste. S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S16 - Keep away from sources of ignition. S6 - Keep under ... (there follows the name of an inert gas). S8 - Keep container dry. |
| UN IDs | UN 3392 4.2/PG 1 |
| WGK Germany | 2 |
| FLUKA BRAND F CODES | 1-10 |
| TSCA | Yes |
| HS Code | 29319090 |
| Hazard Class | 4.3 |
| Packing Group | II |
phenyl-lithiu - Reference Information
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| introduction | phenyl lithium is an organolithium compound. Organolithium compounds are an important class of organometallic compounds, which were prepared by K.Ziegler using the reaction of organic halides and metal lithium as early as 1929, and then applied to organic synthesis. |
| use | phenyl lithium is an organometallic compound, which can be used as an important synthetic reagent and plays an important role in basic theoretical research and industrial synthesis. |
Last Update：2024-04-10 22:29:15
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