shirlan(zeneca)
Fluazinam
CAS: 79622-59-6
Molecular Formula: C13H4Cl2F6N4O4
shirlan(zeneca) - Names and Identifiers
shirlan(zeneca) - Physico-chemical Properties
| Molecular Formula | C13H4Cl2F6N4O4 |
| Molar Mass | 465.09 |
| Density | 1.766±0.06 g/cm3(Predicted) |
| Melting Point | 100-102° |
| Boling Point | 376.1±42.0 °C(Predicted) |
| Flash Point | 2°C |
| Water Solubility | 1.7 mg l-1 (25 °C) |
| Vapor Presure | 1.5 x 10-3 Pa (25 °C) |
| Appearance | neat |
| Color | Light yellow to Amber to Dark green |
| Merck | 14,4117 |
| BRN | 4772672 |
| pKa | 7.11(at 25℃) |
| Storage Condition | 2-8°C |
| Refractive Index | 1.571 |
| MDL | MFCD00214168 |
| Physical and Chemical Properties | The appearance was yellow crystals. m.p.115 -117 °c, relative density 1.757(20 °c), vapor pressure 1.47 x 10-3Pa (25 °c). Solubility in organic solvent at 25 ℃: ethyl acetate 680g/L, acetone 470g/L, toluene 410g/L, dichloromethane 3390g/L, ethanol 120g/L, cyclohexane 14g/L, N-hexane 12g/L, 1, 2-propanediol 8.6g/L; Solubility in water: 0.1mg/L (pH = 5.0), 1.7mg/L (pH = 6.8)> 1000mg/L (pH = 11). It is stable to acid, alkali and heat, and unstable to light. |
| Use | Very effective against Alternaria, Botrytis, Phytophthora, uniaxial, Sclerotinia, and melanoblasts |
shirlan(zeneca) - Risk and Safety
| Risk Codes | R23 - Toxic by inhalation R41 - Risk of serious damage to eyes R43 - May cause sensitization by skin contact R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R36 - Irritating to the eyes R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R11 - Highly Flammable R38 - Irritating to the skin R20 - Harmful by inhalation R63 - Possible risk of harm to the unborn child |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S36/37 - Wear suitable protective clothing and gloves. S16 - Keep away from sources of ignition. S63 - S57 - Use appropriate container to avoid environmental contamination. S56 - Dispose of this material and its container at hazardous or special waste collection point. S38 - In case of insufficient ventilation, wear suitable respiratory equipment. S28 - After contact with skin, wash immediately with plenty of soap-suds. S27 - Take off immediately all contaminated clothing. S24/25 - Avoid contact with skin and eyes. S20/21 - S13 - Keep away from food, drink and animal foodstuffs. |
| UN IDs | UN 2811 |
| WGK Germany | 3 |
| RTECS | UR8085000 |
| HS Code | 29333990 |
| Hazard Class | 6.1 |
| Packing Group | II |
shirlan(zeneca) - Reference Information
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Overview | fluxamine is a heterocyclic fungicide. The original drug is yellow crystal with melting point of 115~117 ℃. Protective fungicides, against Alternaria, Botrytis (especially those that have developed resistance to benzimidazole, dicarboximides), Phytophthora, uniaxial mold, Sclerotinia, black Star bacteria was effective. No inhalation, no therapeutic effect, but very resistant to rain erosion, residual effect is a good foliar spraying Agent, and can also cure spider mites. Soil treatment can also be effective in the prevention and control of Cruciferae and Rhizopus nigricans caused by the Rice Quill, when used in fruit trees, vegetables, plant safety, but greenhouse cucumber with caution. |
| pharmacological action | fluxamine inhibits spore germination, hyphal breakthrough, growth and sporulation inhibit the infection process at all stages. Fluridinamine (sirlan, IKF-1216) was first developed by ishiwon, Japan, and has been further developed. According to the analysis of its characteristics, it belongs to 2,6-dinitroaniline is a low toxicity bactericide, and it also has good protective properties. And flumidamine also has a broad spectrum of antibacterial activity, for the genus Alternaria, Botrytis, phytophhora, the diseases caused by uniaxial mildew and nuclear disc mold have good control effect, especially in the prevention and control of gray mold. |
| toxicity | fluxamine has low toxicity to mammals and most terrestrial organisms such as birds, bees, earthworms, but highly toxic to fish. Flumidamine is moderately irritating to the skin and eyes and may lead to increased sensitivity after contact with the skin. Acute oral LD50>5000mg/kg in rats and mice, mutagenic effect showed that: the recombinant defect test, Ames test was negative. Carp LC500.13 (0.15)mg/L (48h). |
| protective fungicide | , it is effective against streptavidin, Botrytis (especially those that have developed resistance to benzimidazole, dicarboximides), Phytophthora, uniaxial mold, Sclerotinia sclerotiorum, and Black Star. No inhalation, no therapeutic effect, but very resistant to rain erosion, residual effect is a good foliar spraying Agent, and can also cure spider mites. Soil treatment can also be effective in the prevention and control of Cruciferae and Rhizopus nigricans caused by the Rice Quill, when used in fruit trees, vegetables, plant safety, but greenhouse cucumber with caution. Acute oral toxicity to rats LD50>5000 mg/kg, mutagenicity test, recombinant defect determination, Aines test showed negative reaction, fish toxicity carp TLM(48 h)0.13mg/kg.|
| mode of action | protective sterilization and resistance to rain erosion. |
| control object | is often used to control potato and pepper blight. This product is very effective against the genus Alternaria, Botrytis, Phytophthora, uniaxial mildew, anti-disc genus and Black Star genus; against benzimidazole and dicarboximide fungicides Botrytis cinerea also has good effect, long duration; Also can control Cruciferae plant root swollen disease, Rhizopus caused by Rice quetius, it also has the effect of treating mites. |
| method of use | 50 ~ 100gai/ha dose spray, can control the disease caused by botrytis; 125~12.5 Gai/ha soil treatment can control the root nodule disease, ~ 20mg AI/L soil dosage can control the root mould disease. |
| precautions | easy to cause damage to the melon, please be careful not to scatter the liquid to the adjacent melon land when using; this agent may be sensitive to people with allergic skin. Personnel with allergic constitution should not carry out drug application; When it is rainy and the trees are wet, do not carry out drug application; Pruning, fertilization, bagging and other work should be completed as far as possible before drug application; Avoid long-term operation at high temperature and high humidity. |
| Use | pyridinamine derivative, dinitroaniline fungicide. No therapeutic effect and absorption activity, is a broad-spectrum and efficient protective fungicide. It is very effective against Alternaria, Phytophthora, uniaxial, Sclerotinia, and melanoblasts. It also has good effect on Botrytis cinerea which is resistant to benzimidazole and dicarboximide fungicides, and also has good effect on rice Seroquel caused by rhizopus. This product is very resistant to rain erosion, long residual period. In addition to control the role of phytophagous mites. Because the β-trifluoromethylaminopyridine moiety plays a unique role in delivering the compound to the active site of pathogenic bacteria, it can inhibit the germination, infiltration, hyphal growth and spore formation of pathogen spores during infection. The dosage of 124.5 ~ 250.5g active ingredient/hm2 was used for prevention and control of Rhizopus disease, and 187.5 ~ 300mg/L soil was used for prevention and control of Rhizopus disease. very effective as a protective fungicide against Alternaria spp., Botrytis spp., Phytophthora spp., uniaxial spp., Sclerotinia spp, prevention and treatment of diseases caused by Botrytis cinerea, Cruciferae root-swollen disease, Rice quakehead disease. Formulation 0.5% powder, 50% wettable powder, 50% suspension |
| production method | 2, 6-dichloro-4-trifluoromethylaniline is chlorinated in acetic acid solution at 10 °c, 2,5, 6-trichloro-4-trifluoromethylaniline is formed, the product is dissolved in acetic acid, and stirred with hydrogen peroxide and a small amount of concentrated sulfuric acid at room temperature for 8H to form a crystalline product, nitric acid and fuming sulfuric acid were added and cooled to form 2, 6-dinitro-4-trifluoromethyl-5-chloroaniline at 100 °c. Then, the mixture was added to a mixture of 2-amino-3-chloro-5-trifluoromethylpyridine, dry tetrahydrofuran and potassium hydroxide at 5 ° C. For 16h at room temperature to obtain the flumidine amine. FIG. 2 is a chemical reaction scheme for preparing fluoropyridinamine from 2, 6-dichloro-4-trifluoromethylaniline. |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-09 15:16:52
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Multiple Specifications
Product Name: Fluazinam Visit Supplier Webpage Request for quotationCAS: 79622-59-6
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
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