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sodiumbisulfate(sodiumhydrogen

Sodium bisulfate

CAS: 7681-38-1

Molecular Formula: NaHSO4

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sodiumbisulfate(sodiumhydrogen - Names and Identifiers

Name Sodium bisulfate
Synonyms nitercake
NITRE CAKE
Sodium bisulfate
Sodiumhydrogensulfate
sodium hydrogensulfate
sodium hydrogen sulfate
sodium hydrogen sulphate
sulfuricacid,monosodiumsalt
sodiumbisulfate(sodiumhydrogen
Sodium hydrogen sulfate technical grade
CAS 7681-38-1
EINECS 231-665-7
InChI InChI=1/Na.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+1;/p-1

sodiumbisulfate(sodiumhydrogen - Physico-chemical Properties

Molecular FormulaNaHSO4
Molar Mass120.06
Density2.1
Melting Point315 °C
Water Solubilitysoluble in 2 parts H2O, 1 part boiling H2O; decomposes in alcohol to sodium sulfate and H2SO4 [MER06]
AppearanceGranules
ColorWhite to light yellow
Merck13,8658
StabilityStable. Incompatible with strong bases, strong oxidizing agents, sodium carbonate, sodium hypochlorite. May decompose upon exposure to moist air or water.
SensitiveHygroscopic
Physical and Chemical PropertiesColorless monoclinic crystal or white powder. Soluble in cold water, its aqueous solution is acidic.

sodiumbisulfate(sodiumhydrogen - Risk and Safety

Hazard SymbolsXi - Irritant
Irritant
Risk Codes41 - Risk of serious damage to eyes
Safety DescriptionS24 - Avoid contact with skin.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
UN IDs3260
WGK Germany1
RTECSVZ1860000
FLUKA BRAND F CODES3
TSCAYes
HS Code28331900
Hazard Class8
Packing GroupII

sodiumbisulfate(sodiumhydrogen - Nature

Open Data Verified Data

colorless monoclinic crystal or white powder. The relative density was 2. 103. Melting point 58. 54 (0.5) °c. When hot water and alcohol is decomposed. Soluble in cold water, its aqueous solution is acidic. Deliquescence in air. When the crystal water is lost by heating, the anhydrous substance is further decomposed into sodium pyrosulfate by heating.

Last Update:2024-01-02 23:10:35

sodiumbisulfate(sodiumhydrogen - Preparation Method

Open Data Verified Data
  1. sulfate Mirabilite Method: sulfuric acid and anhydrous mirabilite reaction, after filtration, crystallization, separation, drying, prepared products.
  2. crude sodium bisulfate refining method: in the production of chromic anhydride, by-product crude sodium bisulfate, molten sodium bisulfate after removing chromic anhydride, and then by leaching, concentration and crystallization, sodium bisulfate is prepared.
Last Update:2022-01-01 11:04:17

sodiumbisulfate(sodiumhydrogen - Use

Open Data Verified Data

dyeing and printing industry as a dyeing aid for acid dyes. The smelting industry is used as a flux for the decomposition of minerals. The pharmaceutical industry is used as a component of disinfectants and detergents. The chemical industry is used as a raw material for the manufacture of sulfate and sodium alum. In addition, it is also used in oil drilling and soil improvement.

Last Update:2022-01-01 11:04:16

sodiumbisulfate(sodiumhydrogen - Safety

Open Data Verified Data

packed in plastic woven bags lined with two layers of polyethylene plastic bags, each with a net weight of sokg. Acid corrosion products. Risk code: GB 8.1 class 81509. UNNo.1821; IMDG CODE page 8125, class 8.1. Store in a ventilated, dry warehouse. Pay attention to moisture. To prevent rain during transport. In case of fire, it can be suppressed by water and various fire-retardants.

Last Update:2022-01-01 11:04:17

sodiumbisulfate(sodiumhydrogen - Reference Information

EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
Introduction sodium bisulfate, also known as sodium acid sulfate, is an inorganic compound with the chemical formula of NaHSO4 and white monoclinic crystals, it is hygroscopic, the aqueous solution is acidic, and the pH of 0.1mol/L sodium hydrogen sulfate solution is about 1.4.
Application
The application of sodium bisulfate is as follows:

1. Used as a flux and disinfectant, and for the preparation of sulfate and sodium alum.
2. Used as mineral decomposition flux, acid dye dyeing agent and preparation of sulfate and sodium vanadium, also used in the manufacture of toilet cleaner, deodorant, disinfectant.

3. Determination of bromine, iodine, copper and titanium dioxide. Mineral analysis. Household Cleaner (45% solution), extraction of metallic silver; Reduce the alkalinity of swimming pool water; Pet food.
preparation sodium hydroxide and sulfuric acid are mixed in an amount of substances such as sodium hydroxide and sulfuric acid to obtain sodium hydrogen sulfate and water. NaOH H2SO4 → NaHSO4 H2O sodium chloride (salt) and sulfuric acid can react at high temperature to produce sodium bisulfate and hydrogen chloride gas. NaCl H2SO4→ NaHSO4 HCl
identification test According to IT 29, sulfate identification test was positive.
content analysis accurately weigh about 5g of sample, dissolve in about TS-167 of water, add several drops of phenolphthalein test solution (), titration with 1mol/L sodium hydroxide. Per mL of 1mol/L sodium hydroxide corresponds to sulfuric acid (H2SO4)49.04mg or sodium hydrogen sulfate (NaHSO4)120.06mg.
usage limit GB 2760-2001: water preparation, 50mg/kg (13.7mg/kg in terms of sodium).
Use used as analytical reagent and melting agent
used as mineral decomposition flux, disinfectant, dyeing aids and preparation of sodium sulfate and sodium alum, etc.
reagents for analysis and flux
category corrosive article
flammability hazard characteristics non-combustible; Toxic sulfur oxide and sodium oxide smoke emitted by decomposition in fire scene
storage and transportation characteristics warehouse ventilation and low temperature drying
fire extinguishing agent large amount of water
Last Update:2024-04-10 22:29:15
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