Name | Zinc stearate |
Synonyms | Synpro 8 talculinz Talculin Z stavinorzn-e Afco-chem ZNS Zinc stearate stearatedezinc Synpro stearate zinc octadecanoate Zinc Stearate, Zno |
CAS | 557-05-1 |
EINECS | 209-151-9 |
InChI | InChI=1/2C18H36O2.Zn/c2*1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20;/h2*2-17H2,1H3,(H,19,20) |
Molecular Formula | C36H70O4Zn |
Molar Mass | 632.33 |
Density | 1.095g/cm3 |
Melting Point | 128-130 °C (lit.) |
Boling Point | 240℃[at 101 325 Pa] |
Flash Point | 180℃ |
Water Solubility | Insoluble |
Solubility | alcohol: insoluble(lit.) |
Vapor Presure | 0Pa at 25℃ |
Appearance | Powder |
Color | White |
Exposure Limit | ACGIH: TWA 10 mg/m3; TWA 3 mg/m3OSHA: TWA 15 mg/m3; TWA 5 mg/m3NIOSH: TWA 10 mg/m3; TWA 5 mg/m3 |
Merck | 14,10158 |
BRN | 3919706 |
Storage Condition | Inert atmosphere,Room Temperature |
Stability | Stable. Incompatible with strong oxidizing agents. |
MDL | MFCD00013031 |
Physical and Chemical Properties | The appearance of fine white powder, feel smooth, no sand, fat odor, easy moisture absorption, non-toxic, smooth feeling, flammable, insoluble in water, soluble in hot ethanol, turpentine, benzene and other organic solvents. In the case of strong acid decomposition of stearic acid and the corresponding zinc salts. |
Use | It is used in the pharmaceutical industry, in the formulation of curing oils and lubricants, and also as a paint desiccant. For the processing of PVC and rubber non-toxic products, with calcium stearate, barium stearate and synergistic effect, can effectively improve the light thermal stability of PVC and rubber products, PVC processing dosage is usually less than 1; for rubber products, but also for PP, PE, PS, EPS polymerization additives and pencil lead manufacturing, the general dosage of 1~3. |
Hazard Symbols | Xi - Irritant |
Risk Codes | 37 - Irritating to the respiratory system |
Safety Description | S22 - Do not breathe dust. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S38 - In case of insufficient ventilation, wear suitable respiratory equipment. S24/25 - Avoid contact with skin and eyes. |
WGK Germany | - |
RTECS | ZH5200000 |
TSCA | Yes |
HS Code | 29157090 |
Toxicity | LD50 oral in rat: > 10gm/kg |
This line was prepared by reacting stearic acid with zinc. Mainly a mixture of zinc stearate (C36H7004Zn) and zinc palmitate (C32H6204Zn). The zinc oxide (ZnO) content should range from 12.5% to 14.0%.
take this product l.Og, add ethanol 5ml shake, then add water 20ml and phenol red indicator solution 0.1ml, so that the solution becomes yellow by consumption of hydrochloric acid titration solution (O. 1 mol/L) should not exceed the volume of 0.30ml; Or the solution becomes red sodium hydroxide titration solution consumed (0.lmol/L) should not exceed 0 .10ml.
0.20g of the residue obtained under the color of the solution was taken, and a mixed liquid of ethanol-diethyl ether (1: 1) was added [phenolphthalein indicator liquid l was added immediately before use. Oml, with sodium hydroxide titration solution (0.1 mol/L) to micro pink] 25ml to dissolve, measured according to law (General 0713), acid value should be 195~210.
Take 5.0g of this product, add 50ml of ether and nitric acid solution (l.l -10) 40ml, heated to reflux until the solution was clear, allowed to cool, transferred to a separatory funnel, shaken, and placed in layers. The ether layer was extracted twice with water, 4ml each time; The ether layer was evaporated to dryness, and the residue was dried at 105 ° C. For later use; All the aqueous layers were combined, washed with 15ml of ether, and the ether layer was discarded, the water layer is washed off with ether on the water bath, allowed to cool, transferred to a 50ml measuring flask, diluted with water to the scale, and then shaken to serve as a test solution, which is used for color development, it shall not be deeper in comparison with the yellow No. 1 Standard Colorimetric solution (General rule 0901 first method).
take 0.5g of the residue obtained under the color item of the solution, Add 10ml of chloroform to dissolve it, and check according to law (General rule 0901 and general rule 0902). The solution should be clear and colorless. If the color is developed, it shall not be deeper than the yellow No. 2 Standard Colorimetric solution (General rules 0901 first method).
take 2.0ml of the test solution prepared under the color item of the solution, check according to law (General rule 0801), and compare with the control solution made of the standard gasification sodium solution, no more concentrated (0.025%).
take 1.0ml of the test solution prepared under the color item of the solution, put it in a 50ml measuring flask, dilute it to the scale with water, and shake it well. Take another 12.5, check according to law (General rule 0802), and the standard potassium sulfate solution 1 .5ml made of the control solution, not more concentrated (0.6%).
The sample solution prepared under the color item of the precise measurement solution 2 0 .0M l, put it in a 50ml measuring flask, dilute to the scale with nitric acid solution (1.1-10), shake well, and use it as a test solution by atomic absorption spectrophotometry (General 0406), measured at a wavelength of 228.8nm. In addition, cadmium standard solution was diluted with nitric acid solution (1.1-10) to make a reference solution containing 0.2ug of cadmium per 1 ml, and the same method was used for determination. The absorbance of the test solution shall not be greater than that of the reference solution (0.0005%).
The test solution prepared under the color of the solution was taken and measured by atomic absorption spectrophotometry (General 0406) at a wavelength of 217 · Onm. In addition, take the appropriate amount of standard lead stock solution, and dilute with nitric acid solution (1.1-10) to make the reference solution containing 2.5 of lead in each lml, the absorbance of the test solution shall not be greater than that of the reference solution (0.0025%).
take 3.33g of this product, add 50ml of water and 5ml of sulfuric acid, slowly boil until the oil layer is clear and the volume of the solution is reduced to about 25ml, filter and cool while hot, dilute to 50ml with water, measure 20ml, add water 8ml, inspection according to law (General Principles 0822 second law), should meet the requirements (0.000 15%).
weigh about 1g of this product accurately, add 50ml of 0.05 mo1/L sulfuric acid solution, boil for at least 10 minutes until the oil layer is clear, and make up water to the initial volume if necessary. Cool, filter, wash the filter and beaker with water until the wash solution is not acidic to the blue litmus paper; Combine the filtrate and wash solution, and add ammonia-gasified ammonium buffer (6.75g of gasified ammonium, add water to dissolve, add 57ml of concentrated ammonia solution, dilute to 100ml with water) 15ml and a small amount of Chrome Black T indicator, heat to 40°C, and titrate with ethylene diamine tetraacetic acid disodium titration solution (0.05 mol/L) until the solution is pure blue. Each 1 ml of ethylene diamine tetraacetic acid disodium titration solution (0.05mol/L) corresponds to 4.069mg of ZnO.
pharmaceutical excipients, lubricants, etc.
sealed storage.
LogP | 4.64 at 25℃ |
NIST chemical information | information provided by: webbook.nist.gov (external link) |
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
Overview | zinc stearate is a white, light, fine powder. Molecular formula ZN(C17H35COO)2, molecular structure rcooznocr (R is a mixed alkyl group in industrial stearic acid), flammable, specific gravity 1.095, auto-ignition point 900 ℃, density 1.095, melting point 130 ℃, a smooth feeling. Insoluble in water, ethanol, ether, soluble in hot ethanol, turpentine, benzene and other organic solvents and acids. Zinc stearate is dissolved when heated in an organic solvent and cooled to form a gum, which is decomposed into stearic acid and the corresponding zinc salt when exposed to a strong acid. There are lubricity, hygroscopicity, non-toxic, micro-irritating, non-polluting, non-hazardous characteristics. Zinc stearate and calcium stearate can be separated by the property that zinc stearate is soluble in benzene and calcium stearate is insoluble in benzene. zinc stearate is insoluble in polar solvents but is highly soluble in chlorinated hydrocarbons of the aromatic compound agent when heated. They are mainly used in the plastic and rubber industry and are used as mold release agents and lubricants due to their good compatibility. |
How to remove residual zinc stearate from aluminum surface processing | the residual zinc stearate is generally processed by grinding. The substrate may be damaged by the use of inducing acids. |
reference quality standard | HG /T3667-2000 project top grade first grade qualified product appearance white light powder moisture ≤ 2% zinc content,% 10.3~11.3 10.3~11.3 10.0~11.5 free acid%,≤ 0.8 1.0 1.5% heating loss%,≤ 0.8 1.0 1.5 melting point, ℃ 120±5 120±5 120±5 particle size (through Test Sieve) ≥ 99.0 (0.045) 99.5 (0.075) 95.0 (0.075) |
function and use | zinc stearate has good thermal stability, small initial coloring, good light stability and synergistic effect with calcium stearate and barium stearate, with the role of foam, can be used for foaming products as a foaming aid, can be used as a lubricant for cosmetics flour lubricant glue powder plastic products lubricant zinc stearate used as a stabilizer for polyvinyl chloride. With barium-cadmium soap, mainly used for soft products, is characterized by inhibition of initial coloring, to avoid sulfide pollution. Zinc stearate can also be used as Styrene (polystyrene and ABC, SAN resin), phenolic resin, amino resin and other thermosetting plastics and polyester plastic, transparent products lubricants and mold release agents. In the rubber industry, it is used as a lubricant and anti-blocking agent for rubber compounds, and as an activator of vulcanization catalyst. Polishing agent for textile products paint industry enamel industry used as leveling agent |
Use | used as a softening lubricant for rubber products, as a polishing agent for textiles, PVC plastic stabilizer used as a stabilizer for PVC plastic products, rubber products softener used in the pharmaceutical industry, curing oil and lubricant formulation, also used as paint desiccant. For the processing of PVC and rubber non-toxic products, with calcium stearate, barium stearate and synergistic effect, can effectively improve the light thermal stability of PVC and rubber products, PVC processing dosage is usually less than 1; for rubber products, but also for PP, PE, PS, EPS polymerization additives and pencil lead manufacturing, the general dosage of 1~3. stabilizer; Lubricant; Grease; Accelerator; Thickener used in petrochemical industry polyethylene, polystyrene, polyvinyl chloride and high-grade chemical fiber color master dispersant, heat stabilizer. For color Master (grain) as a heat stabilizer, dispersant, lubricant. |
spontaneous combustion temperature | 1454 ° F. |
toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |