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trans-2-hexenal

trans-2-hexenal

CAS: 6728-26-3

Molecular Formula: C6H10O

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trans-2-hexenal - Names and Identifiers

Name trans-2-hexenal
Synonyms AI3-35157
CCRIS 4565
BRN 1699684
FEMA No. 2560
2-trans-Hexenal
2-Hexenal, (E)-
trans-2-hexenal
trans-Hex-2-enal
2-Hexenal, (2E)-
beta-Propyl acrolein
trans-2-Hexenal (leaf aldehyde)
4-01-00-03468 (Beilstein Handbook Reference)
CAS 6728-26-3
EINECS 229-778-1
InChI InChI=1/C6H10O/c1-2-3-4-5-6-7/h4-6H,2-3H2,1H3/b5-4+

trans-2-hexenal - Physico-chemical Properties

Molecular FormulaC6H10O
Molar Mass98.14
Density0.846
Melting Point-78°C (estimate)
Boling Point146-149℃
Flash Point35℃
Water SolubilityINSOLUBLE
Vapor Presure10 mm Hg ( 20 °C)
Vapor Density3.4 (vs air)
AppearanceForm Liquid, color Clear colorless to light yellow
Storage Condition2-8℃
Refractive Index1.444
MDLMFCD00007008
Physical and Chemical PropertiesChemical properties pale yellow liquid. It is rich in fresh fruits and fragrant green leaves. There are two isomers, cis and trans. Boiling point 150~152 ℃, or 47 ℃(2266 Pa), flash point 3 7.8 ℃. Soluble in ethanol, propylene glycol and most non-volatile oils, very slightly soluble in water. Natural products exist in tea, mulberry leaves, radish leaves and other oils, as well as cucumbers, apples, peaches, orange peel, strawberries, egg fruits, papaya, etc.
UseUse 1, GB 2760~96 for the allowable use of edible spices. Mainly used for the preparation of raspberry, mango, egg, apple, strawberry flavor. 2, the product has a fresh green leaf fragrance, can be used for artificial flowers, essential oils, all kinds of flower fragrance blend spices. Some derivatives of Qingye aldehyde are also spices, such as the dimethyl acetal and diethyl acetal of Qingye aldehyde; The hydrogenation of Qingye aldehyde to produce the anti-hexenyl alcohol (green leaf alcohol), oxidation of the resulting trans-hexenoic acid -2 and so on.

trans-2-hexenal - Risk and Safety

Hazard SymbolsXn - Harmful
Harmful
Risk CodesR10 - Flammable
R21/22 - Harmful in contact with skin and if swallowed.
Safety DescriptionS16 - Keep away from sources of ignition.
S36/37 - Wear suitable protective clothing and gloves.
UN IDsUN 1988
WGK Germany2
RTECSMP5900000
TSCAYes
HS Code29121900
Hazard Class3
Packing GroupIII

trans-2-hexenal - Upstream Downstream Industry

Raw MaterialsAcetal
Hexanal
Downstream Products3-methylhexanal
1,1-Diethoxybutane
METHYL TRANS-2-HEXENOATE, 98
TRANS-2-HEXENAL DIMETHYL ACETAL
2-Ethylfuran
1,2-Ethenediylbis(oxy) (9CI)

trans-2-hexenal - Reference

Reference
Show more
1. [IF=6.475] Dong-Yu Shen et al."Characterization of odor-active compounds in moso bamboo (Phyllostachys pubescens Mazel) leaf via gas chromatography-ion mobility spectrometry, one- and two-dimensional gas chromatography-olfactory-mass spectrometry, and electronic nos

trans-2-hexenal - Introduction

Soluble in ethanol, dipropyl glycol and non-hair oil. Insoluble in water.
Last Update:2022-10-16 17:27:52

trans-2-hexenal - Nature

FEMA 2560 | HEXEN-2-AL
JECFA Number 1353
BRN 1699684
NIST chemical information 2-Hexenal, (E)-(6728-26-3)
EPA chemical information 2-Hexenal, (2E)- (6728-26-3)
Last Update:2024-04-10 22:29:15

trans-2-hexenal - Production method

1. It is prepared by bromination, acetalization, debromination and hydrolysis of acetaldehyde.
2. Natural products are free by steam distillation to obtain crude products, and then extracted and refined by acetone.
It is obtained by reacting hexanal with ethylene glycol after bromination, and then hydrolyzing.

Last Update:2024-04-09 21:11:58
trans-2-hexenal
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View History
trans-2-hexenal
邻苯甲酰磺酰亚胺钠盐二水合物
N-[(2-CHLORO-1-PHENYLIMINOMETHYL-1-CYCLOHEXENE-3-YLIDENE)METHYL]ANILINE HYDROCHLORIDE
2-Bromophenylphenyl ether
tert-butyl (2-(2-(prop-2-yn-1-yloxy)ethoxy)ethyl)carbamate
4-环丙基萘-1-胺草酸盐
氨甲酰苯卓
Epoxycyclooctane for synthesis
4-(三丁基锡基)噻唑
4-(2-氨基乙基)苯腈盐酸盐
Raw Materials for trans-2-hexenal
Acetal
Hexanal
Downstream Products for trans-2-hexenal
3-methylhexanal
1,1-Diethoxybutane
METHYL TRANS-2-HEXENOATE, 98
TRANS-2-HEXENAL DIMETHYL ACETAL
2-Ethylfuran
1,2-Ethenediylbis(oxy) (9CI)
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