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tributyl(pyridin-2-yl)stannane

Tributylpyridyltin

CAS: 17997-47-6

Molecular Formula: C17H31NSn

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tributyl(pyridin-2-yl)stannane - Names and Identifiers

Name Tributylpyridyltin
Synonyms stannyL
2-(Tri-n-butyL
Tributylpyridyltin
TRIBUTYL(2-PYRIDYL)TIN
2-pyridyltri-n-butyltin
Tri-n-butyl(2-pyridyl)tin
TRI-N-BUTYL(2-PYRIDYL)TIN
2-(tributylstannyl)pyridine
2-TRI-N-BUTYLSTANNYLPYRIDINE
2-(tributylstannanyl)pyridine
tributyl(pyridin-2-yl)stannane
(Pyridin-2-yl)(tributyl)tin, (Pyridin-2-yl)tributylstannane
CAS 17997-47-6
EINECS 628-762-5
InChI InChI=1/C5H4N.3C4H9.Sn/c1-2-4-6-5-3-1;3*1-3-4-2;/h1-4H;3*1,3-4H2,2H3;/rC17H31NSn/c1-4-7-14-19(15-8-5-2,16-9-6-3)17-12-10-11-13-18-17/h10-13H,4-9,14-16H2,1-3H3
InChIKey GYUURHMITDQTRU-UHFFFAOYSA-N

tributyl(pyridin-2-yl)stannane - Physico-chemical Properties

Molecular FormulaC17H31NSn
Molar Mass368.14
Density1.15
Melting Point132-135 °C
Boling Point134 °C
Flash Point>110°C
Vapor Presure1.43E-05mmHg at 25°C
Specific Gravity1.142
Exposure LimitACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
BRN479329
pKa5.21±0.19(Predicted)
Storage Condition-20°C
Sensitive7: reacts slowly with moisture/water
Refractive Index1.5130
MDLMFCD00052052

tributyl(pyridin-2-yl)stannane - Risk and Safety

Risk CodesR21 - Harmful in contact with skin
R25 - Toxic if swallowed
R36/38 - Irritating to eyes and skin.
R48/23/25 -
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R10 - Flammable
Safety DescriptionS35 - This material and its container must be disposed of in a safe way.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. 
S60 - This material and its container must be disposed of as hazardous waste.
UN IDs2788
WGK Germany3
TSCANo
HS Code29333990
Hazard NoteToxic
Hazard Class6.1
Packing GroupIII

tributyl(pyridin-2-yl)stannane - Introduction

Open Data Unverified Data

A Tributylpyridyltin is an organic compound, also known as TBPP. Its chemical formula is C17H31NSn, and its structure contains a tin atom and a pyridine ring, as well as three n-butyl methyl groups.

Nature:
1. Appearance: common colorless to light yellow liquid.
2. Density: 1.15
3. Melting point:-132-135 °C
4. Boiling point: 134 °C
5. Solubility: Soluble in common organic solvents, such as ethanol, acetone, etc.

Use:
1. Catalyst: The organic tin as the reaction liquid of the catalyst participates in the esterification, etherification, and Ketonization reactions, and is widely used in the field of organic synthesis.
2. Plasticizer: Used as a plasticizer for plastics, it can improve the flexibility and processability of plastics.
3. Bacteriostatic agent: It has good antibacterial properties and can be used in fabrics, coatings and preservatives.

Method:
A commonly used preparation method is to react n-butyl methyl amine with methyl tin chloride, and then react with pyridine chloride to obtain Tributylpyridyltin.

Safety Information:
1. TBPP is an organotin compound, should avoid inhalation, swallowing and skin contact. Appropriate protective measures should be used during work, such as wearing gloves and protective clothing.
2. Store away from fire and oxidant to prevent fire and explosion.
3. In case of leakage, use non-combustible materials to absorb and dispose of the waste liquid properly.
4. Relevant regulations and safe operating procedures should be followed, such as gas, liquid or solid waste should be disposed of in accordance with local regulations.

Last Update:2024-04-09 19:43:38
tributyl(pyridin-2-yl)stannane
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