tripropan-2-ylsilane
Triisopropylsilane
CAS: 6485-79-6;6459-79-6
Molecular Formula: C9H22Si
tripropan-2-ylsilane - Names and Identifiers
| Name | Triisopropylsilane |
| Synonyms | PD-Tips HandyStep Triisopropylsilane tripropan-2-ylsilane Three isopropylsilane Triisopropylsilane(L) tris(propan-2-yl)silane Silane, tris(1-methylethyl)- Triisopropylsilane Synonyms Triisopropylhydrosilane |
| CAS | 6485-79-6 6459-79-6 |
| EINECS | 464-880-1 |
| InChI | InChI=1/C9H22Si/c1-7(2)10(8(3)4)9(5)6/h7-10H,1-6H3 |
| InChIKey | YDJXDYKQMRNUSA-UHFFFAOYSA-N |
tripropan-2-ylsilane - Physico-chemical Properties
| Molecular Formula | C9H22Si |
| Molar Mass | 158.36 |
| Density | 0.773 g/mL at 25 °C (lit.) |
| Boling Point | 84-86 °C/35 mmHg (lit.) |
| Flash Point | 99°F |
| Water Solubility | Immiscible with water. |
| Vapor Presure | 1.37mmHg at 25°C |
| Appearance | liquid |
| Specific Gravity | 0.773 |
| Color | colorless |
| BRN | 1733718 |
| Storage Condition | Store below +30°C. |
| Sensitive | 3: reacts with aqueous base |
| Refractive Index | n20/D 1.434(lit.) |
| Physical and Chemical Properties | Colorless liquid, B .P.84-85 ℃(35mmHg), F.P.35 ℃,d 0.773.nD201.4340. This product is flammable, irritating |
tripropan-2-ylsilane - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | R10 - Flammable R36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S37/39 - Wear suitable gloves and eye/face protection S16 - Keep away from sources of ignition. |
| UN IDs | UN 1993 3/PG 3 |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 10-21 |
| TSCA | No |
| HS Code | 2931 90 00 |
| Hazard Class | 3 |
| Packing Group | III |
tripropan-2-ylsilane - Reference Information
| preparation | first, the metal magnesium and 2-chloropropane were reacted to synthesize isopropyl magnesium chloride, and then in the presence of weak polar solvent, triisopropylsilane was prepared from isopropylmagnesium chloride and trichlorosilane at low temperature. The invention generates triisopropylsilane by a two-step synthesis method, and when preparing triisopropylsilane, a weak polar solvent that does not affect the solubility of the solvent is used to change the polarity of the solvent, in order to prevent the occurrence of side reactions, the difficult-to-separate impurities in the reaction process are greatly reduced. Finally, high-purity triisopropylsilane can be obtained by simple distillation, and the purity of the product can reach 99%. |
| Use | peptide synthetic protectant. Large Volume isopropyl group (compared with ethyl group) can achieve more selective reduction reaction? Should be (e. G., beta-selective reduction of heterotopic C- phenyl ketals), but not reduce their activity (e. G., trifluoromethane? Sulfonic acid ketone catalytic type reduction etherification). Highly non-? N-heterocyclic carbene complex-catalyzed trans-1, 2-diol? Enantioselective preparation. |
Last Update：2024-04-09 02:00:10
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View History
tripropan-2-ylsilane
54526-01-1
2-diazo-1-naphthol-5-sulfonic acid, ester with novolac
ACID BLUE 41
光引发剂KIP 160
STEVIA REBAUDIANA EXTRACT
Olean-13(18)-en-3-ol, (3β)-
pd134298-38a
(2Z,6E)-Farnesol
3-Hydroxy Citalopram
54526-01-1
2-diazo-1-naphthol-5-sulfonic acid, ester with novolac
ACID BLUE 41
光引发剂KIP 160
STEVIA REBAUDIANA EXTRACT
Olean-13(18)-en-3-ol, (3β)-
pd134298-38a
(2Z,6E)-Farnesol
3-Hydroxy Citalopram