三甲基硅基甲基叠氮化物
Trimethylsilylmethylazide
CAS: 87576-94-1
Molecular Formula: C4H11N3Si
三甲基硅基甲基叠氮化物 - Names and Identifiers
| Name | Trimethylsilylmethylazide |
| Synonyms | Trimethylsilylmethylazide RIMETHYLSILYLMETHYL AZIDE AZIDOMETHYLTRIMETHYLSILANE TRIMETHYLSILYLMETHYL AZIDE Trimethylsilylmethyl azide Silyl Methyl azide triMethyl (azidomethyl)(trimethyl)silane |
| CAS | 87576-94-1 |
| InChI | InChI=1/C4H11N3Si/c1-8(2,3)4-6-7-5/h4H2,1-3H3 |
三甲基硅基甲基叠氮化物 - Physico-chemical Properties
| Molecular Formula | C4H11N3Si |
| Molar Mass | 129.24 |
| Density | 0,87 g/cm3 |
| Boling Point | 92-95°C |
| Flash Point | 6°C |
| Solubility | Sol organic solvents; insol water. |
| Appearance | clear liquid |
| Specific Gravity | 0.87 |
| Color | Colorless to Yellow to Green |
| Storage Condition | Room Temprature |
| Sensitive | 7: reacts slowly with moisture/water |
| Refractive Index | 1.4300 to 1.4340 |
| MDL | MFCD00059964 |
三甲基硅基甲基叠氮化物 - Risk and Safety
| Risk Codes | R11 - Highly Flammable R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. |
| Safety Description | S16 - Keep away from sources of ignition. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
| UN IDs | 1992 |
| Hazard Class | 3 |
| Packing Group | II |
三甲基硅基甲基叠氮化物 - Reference Information
| Use | trimethylsilylmethyl azide is useful as an intermediate in the synthesis of pharmaceuticals. |
| preparation | the preparation of trimethylsilylmethyl azide is as follows: to Stirred (chloromethyl) trimethylsilane (1.0g,8.15mmol,1.0 equiv) in DMF(10ml) was added sodium azide (1.60g,24.6mmol,3.0 equiv) and KI(0.025g, catalyst). Stirring was continued for 10 min at room temperature. The temperature of the reaction mixture was then slowly increased to 60 °c and stirring was continued at 60 °c for 12 hours. After completion of the reaction (10% ethyl acetate in hexane Rf = 0.2, monitored by TLC), the mixture was poured into cold water and extracted with ethyl acetate. The organic extract was washed with water, then brine, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give crude trimethylsilylmethyl azide (1.20g) as a colorless liquid, it was used without further purification and characterization. |
Last Update：2024-04-10 22:29:15
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三甲基硅基甲基叠氮化物
四氨合氯化铂 水合物
NEOPENTYL GLYCOL ADIPATE
(S)-3-((((9H-芴-9-基)甲氧基)羰基)氨基)氨基)-4-羟基丁酸叔丁酯
1-甲基-3-烯丙基溴化咪唑
聚亚甲基聚芳基异氰酸酯
四氨合氯化铂 水合物
NEOPENTYL GLYCOL ADIPATE
(S)-3-((((9H-芴-9-基)甲氧基)羰基)氨基)氨基)-4-羟基丁酸叔丁酯
1-甲基-3-烯丙基溴化咪唑
聚亚甲基聚芳基异氰酸酯