二乙基二硫基氨基甲酸锌
Zinc diethyldithiocarbamate
CAS: 14324-55-1
Molecular Formula: C10H20N2S4Zn
二乙基二硫基氨基甲酸锌 - Names and Identifiers
| Name | Zinc diethyldithiocarbamate |
| Synonyms | EZ ZDC ZDEC etazin ethasan ethazate ancazate et Ethyl Ziram ETHYL ZIMATE ethyl zimate acceleratorzdc AcceleratorZDC Zinc two ethyl two Rubber Accelerator EZ Accelerator EZ powder accelerator ez powder Rubber Accelerator ZDEC ZINC DIETHYLDITHIOCARBAMATE Zinc diethyldithiocarbamate zinc diethyl dithiocarbamate bis(diethyldithiocarbamato)zinc ZINC N,N-DIETHYLDITHIOCARBAMATE bis(diethyldithiocarbamate)zinc bis(diethyldithiocarbamato)-zin bis(diethyldithio-carbamate)zinc zinc bis(diethylcarbamodithioate) diethyl-carbamodithioicacizincsalt bis(diethyldithiocarbamato)zinc[qr] DIETHYLDITHIOCARBAMIC ACID ZINC SALT bis(diethylcarbamodithioato-s,s') zinc carbamodithioic acid, diethyl-, zinc salt bis(diethylcarbamodithioato-s,s')-,(t-4)-zinc |
| CAS | 14324-55-1 |
| EINECS | 238-270-9 |
| InChI | InChI=1/2C5H11NS2.Zn/c2*1-3-6(4-2)5(7)8;/h2*3-4H2,1-2H3,(H,7,8);/q;;+2/p-2 |
| InChIKey | RKQOSDAEEGPRER-UHFFFAOYSA-L |
二乙基二硫基氨基甲酸锌 - Physico-chemical Properties
| Molecular Formula | C10H20N2S4Zn |
| Molar Mass | 361.93 |
| Density | 1,48 g/cm3 |
| Melting Point | 178-181 °C (lit.) |
| Boling Point | 330.6°C (estimate) |
| Flash Point | 204°(400°F) |
| Water Solubility | Insoluble in water. Soluble in benzene carbon disulfide and organic liquids. |
| Vapor Presure | 0.007Pa at 25℃ |
| Appearance | White crystalline powder |
| Specific Gravity | 1.48 |
| Color | White |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
| Sensitive | 4: no reaction with water under neutral conditions |
| MDL | MFCD00064798 |
| Physical and Chemical Properties | White crystals. The melting point of 176 deg C, the relative density of 1.49. Soluble in ether, carbon disulfide, benzene and chloroform, slightly soluble in alcohol, insoluble in water. |
| Use | It is used as a super accelerator for natural and synthetic rubber, especially for butyl rubber, three ethylene propylene rubber and latex. Non-toxic, tasteless, suitable for white or bright color, transparent products. Application in rubber products in contact with food |
二乙基二硫基氨基甲酸锌 - Risk and Safety
| Risk Codes | R22 - Harmful if swallowed R36/37/38 - Irritating to eyes, respiratory system and skin. R43 - May cause sensitization by skin contact R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Safety Description | S24 - Avoid contact with skin. S37 - Wear suitable gloves. S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
| UN IDs | UN 3077 9/PG 3 |
| WGK Germany | 3 |
| RTECS | ZH0350000 |
| TSCA | Yes |
| HS Code | 29302000 |
| Hazard Class | 6.1 |
| Packing Group | III |
| Toxicity | LD50 orl-rat: 3340 mg/kg 28ZPAK -,11,72 |
二乙基二硫基氨基甲酸锌 - Reference Information
| LogP | 3.11 |
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| Origin | In 1912, the Germans Hoffman (Fritz Hofmann), Debrook (K.Delbrhck) and Baogman (M.Bogmann) discovered that dithiocarbamate can be used as a vulcanization accelerator. ZDEZ(ZDC,EZ) is one of the representative products of dithiocarbamate accelerators, and is also a product widely used in rubber and latex products. |
| application | accelerator ZDC is a superaccelerator, suitable for natural rubber and synthetic rubber, and is a good active agent for thiazole and sulfenamide accelerators. |
| product characteristics | accelerator ZDC is a good active agent for thiazole and sulfenamide accelerators. It has a strong activation effect on butyl rubber containing accelerator M, TMTD or the combination of M and TMTD, which can greatly shorten the vulcanization time, and can also be used for ethylene propylene terpolymer, but the activation effect is not as strong as butyl rubber. This product is also used as a non-water-soluble accelerator for latex, which has little effect on the stability of latex. When used as the second accelerator of thiazole accelerator in latex, the obtained product has good aging performance. |
| use | zinc diethyldithiocarbamate is mainly used as a plastic rubber additive. The accelerator ZDC is a superaccelerator for natural rubber and various synthetic rubbers. It is a representative variety of zinc dithiocarbamate salts and a general accelerator for latex. This product is non-polluting, non-discolored, odorless, tasteless, non-toxic, alkaline accelerator has activation effect on it, good dispersibility, can improve the tensile strength and elasticity of vulcanizate. Good dispersibility in rubber can improve the tensile strength and elasticity of vulcanizates. Antioxidants should be added in NR and IR to improve heat resistance. The accelerator ZDC can also be used as an antioxidant for bonding systems. This product is used as a superaccelerator for natural gum and synthetic gum. It is a representative variety of zinc dithiocarbamate promotion and an analytical reagent. It can be used as a super accelerator for natural rubber and synthetic rubber, and can also be used as a general accelerator for latex It can be used as a super accelerator for natural rubber and synthetic rubber, especially suitable for butyl rubber, EPDM and latex. Non-toxic, tasteless, suitable for white or brilliant color, transparent products. Application in rubber products in contact with food Used as an accelerator and analytical reagent for natural and synthetic rubber. |
| Production method | Sodium diethyldithiocarbamate is prepared by condensation of diethylamine and carbon disulfide, and then zinc sulfate (or Zinc chloride) is replaced. Raw material consumption (kg/t) diethylamine 490 carbon disulfide 610 zinc sulfate 510 |
| category | pesticide |
| toxicity classification | poisoning |
| acute toxicity | oral administration-rat LDL0: 3340 mg/kg; Abdominal cavity-mouse LD50: 142 mg/kg |
| stimulation data | eyes-rabbit 100 mg/24 hours moderate |
| flammability hazard characteristics | flammability; combustion produces toxic nitrogen oxides, sulfur oxide smoke; poisoning reaction: strong irritation to eyes, nose, throat |
| storage and transportation characteristics | warehouse ventilation and low temperature drying |
| fire extinguishing agent | dry powder, foam, sand, carbon dioxide, mist water |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-10 22:29:15
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View History
二乙基二硫基氨基甲酸锌
炎痛美新
(2-methylpropyl)lithium
利马前列素
三甲基(4-吡啶基)锡
二环(2.2.1)庚-5-烯-2-甲腈
雀舌黄杨碱B
4-Isobutyl-2-pyrrolidinone (pregabalin lactam impurity)
炎痛美新
(2-methylpropyl)lithium
利马前列素
三甲基(4-吡啶基)锡
二环(2.2.1)庚-5-烯-2-甲腈
雀舌黄杨碱B
4-Isobutyl-2-pyrrolidinone (pregabalin lactam impurity)