二甲氧基双(五氟苯基)硅烷 - Names and Identifiers
Name | dimethoxy[bis(pentafluorophenyl)]silane
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Synonyms | DIMETHOXYBIS(PENTAFLUOROPHENYL)SILANE BIS(PENTAFLUOROPHENYL)DIMETHOXYSILANE Dimethoxy[bis(pentafluorophenyl)]silane dimethoxy[bis(pentafluorophenyl)]silane imethoxy-bis(2,3,4,5,6-pentafluorophenyl)silane DiMethoxy-bis(2,3,4,5,6-pentafluorophenyl)silane Benzene, 1,1'-(dimethoxysilylene)bis[2,3,4,5,6-pentafluoro-
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CAS | 223668-68-6
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InChI | InChI=1/C14H6F10O2Si/c1-25-27(26-2,13-9(21)5(17)3(15)6(18)10(13)22)14-11(23)7(19)4(16)8(20)12(14)24/h1-2H3 |
二甲氧基双(五氟苯基)硅烷 - Physico-chemical Properties
Molecular Formula | C14H6F10O2Si
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Molar Mass | 424.27 |
Density | 1,373 g/cm3 |
Boling Point | 91 °C |
Flash Point | 123°C |
Vapor Presure | 0.0067mmHg at 25°C |
Specific Gravity | 1.373 |
Storage Condition | Room Temprature |
Sensitive | 7: reacts slowly with moisture/water |
Refractive Index | 1.4181 |
二甲氧基双(五氟苯基)硅烷 - Risk and Safety
TSCA | No |
Hazard Class | IRRITANT, CORROSIVE |
二甲氧基双(五氟苯基)硅烷 - Introduction
dimethoxy[bis(pentafluorophenyl)]silane is an organosilicon compound with the chemical formula (cis F) Si (OCIS H f₂). The following is a description of its nature, use, preparation and safety information:
Nature:
-Appearance: colorless liquid
-Molecular weight: 605.15g/mol
-Melting point:-20 ° C
-Boiling point: 100-105 ° C
-Density: 1.628g/cm³
-Solubility: Soluble in organic solvents such as ether, methanol and dichloromethane
Use:
- dimethoxy[bis(pentafluorophenyl)]silane is a commonly used reagent in organic synthesis. It can be used as an introducing agent of silane protecting group to protect or modify some organic functional groups.
-It can also be used as a catalyst precursor for some organic synthesis reactions, such as cross-coupling reactions and coupling reactions.
Method:
- dimethoxy[bis(pentafluorophenyl)]silane can be synthesized in a two-step reaction:
1. Pentafluorophenyl silicone and cadmium were reacted in acetic acid to prepare pentafluorophenyl cadmium compound.
2. The pentafluorophenyl cadmium compound is reacted with methanol under the catalysis of copper sulfate to obtain dimethoxy[bis(pentafluorophenyl)]silane product.
Safety Information:
- dimethoxy[bis(pentafluorophenyl)]silane may irritate the skin and eyes, and direct contact should be avoided.
-When handling, should take appropriate protective measures, such as wearing protective glasses, gloves and laboratory coats.
-When storing, keep it in a tightly sealed container, away from fire and oxidizing agents.
-If it leaks, it should be absorbed with absorbent immediately and the waste should be properly disposed.
Last Update:2024-04-10 22:29:15