Name | isopropenylmagnesium bromide solution |
Synonyms | bromo(prop-1-en-2-yl)magnesium isopropenylmagnesium bromide solution |
CAS | 13291-18-4 |
InChI | InChI=1/C3H5.BrH.Mg/c1-3-2;;/h1H2,2H3;1H;/q;;+1/p-1/rC3H5BrMg/c1-3(2)5-4/h1H2,2H3 |
InChIKey | LFTYALBVGVNGLI-UHFFFAOYSA-M |
Molecular Formula | C3H5BrMg |
Molar Mass | 145.281 |
Density | 0.94 g/mL at 20 °C |
Melting Point | 102-104 °C |
Boling Point | 67 °C |
Flash Point | −36 °F |
Appearance | White to yellow to orange Crystalline Powder |
Use | Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-(?)-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol. |
Risk Codes | R11 - Highly Flammable R14 - Reacts violently with water R15 - Contact with water liberates extremely flammable gases R34 - Causes burns R40 - Limited evidence of a carcinogenic effect R37 - Irritating to the respiratory system R19 - May form explosive peroxides |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S30 - Never add water to this product. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S7 - Keep container tightly closed. S8 - Keep container dry. S16 - Keep away from sources of ignition. |
UN IDs | UN 3399 4.3/PG 1 |
WGK Germany | 1 |
FLUKA BRAND F CODES | 1-3-10-34 |
HS Code | 29319090 |
Raw Materials | H-TBU-GLY-OTBU HCL |
Melting point 102-104°C
Boiling point 67°C
Density 0.94g/mL at 20 c
Flash point & minus;36 °F
Storage conditions 2-8°C
Morphological Crystalline Powder
Color White to yellow to orange
BRN 3587297
InChIKey LFTYALBVGVNGLI-UHFFFAOYSA-M
security information
Dangerous goods mark f, C
Hazard category code 11-14/15-34-40-37-19-14
Safety instructions 26-30-36/37/39-43-45-7/8-16
Dangerous goods transportation number UN 3399 4.3/PG 1
WGK Germany 1
F 1-3-10-34
Customs code 29319090