溴醋酸乙酯
Ethyl bromoacetate
CAS: 105-36-2
Molecular Formula: C4H7BrO2
溴醋酸乙酯 - Names and Identifiers
| Name | Ethyl bromoacetate |
| Synonyms | Antol 2-bromobutanoate ethylbromacetate Ethyl bromacetate ETHYL BROMOACETATE Ethyl bromoacetate ethylbromoethanoate Ethyl 2-bromoacetate ETHYL 2-BROMOACETATE bromoacetated'ethyle ethylmonobromoacetate Ethyl alpha-bromoacetate bromo-aceticaciethylester ethoxycarbonylmethylbromide Ethoxycarbonylmethyl bromide BROMOACETIC ACID ETHYL ESTER Aceticacid,bromo-,ethylester 2-bromoacetic acid ethyl ester α-bromoacetic acid ethyl ester |
| CAS | 105-36-2 |
| EINECS | 203-290-9 |
| InChI | InChI=1/C4H7BrO2/c1-2-3(5)4(6)7/h3H,2H2,1H3,(H,6,7)/p-1 |
| InChIKey | PQJJJMRNHATNKG-UHFFFAOYSA-N |
溴醋酸乙酯 - Physico-chemical Properties
| Molecular Formula | C4H7BrO2 |
| Molar Mass | 167 |
| Density | 1.506g/mLat 25°C(lit.) |
| Melting Point | -38 °C |
| Boling Point | 159°C(lit.) |
| Flash Point | 118°F |
| Water Solubility | Miscible with ethanol, acetone, benzene and ethyl ether. Immiscible with water. |
| Solubility | water: insoluble |
| Vapor Presure | 2.6 mm Hg ( 25 °C) |
| Vapor Density | 5.8 (vs air) |
| Appearance | Liquid |
| Specific Gravity | 1.506 |
| Color | Clear |
| Odor | Pungent odour |
| BRN | 506456 |
| Storage Condition | Store below +30°C. |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents, water, strong acids. |
| Refractive Index | n20/D 1.451(lit.) |
| Physical and Chemical Properties | Density 1.506 melting point -38°C boiling point 159°C refractive index 1.45-1.452 flash point 47°C |
| Use | Used as pharmaceutical, pesticide intermediates |
溴醋酸乙酯 - Risk and Safety
| Hazard Symbols | T+ - Very toxic |
| Risk Codes | 26/27/28 - Very toxic by inhalation, in contact with skin and if swallowed. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S7/9 - S1/2 - Keep locked up and out of the reach of children. |
| UN IDs | UN 1603 6.1/PG 2 |
| WGK Germany | 1 |
| RTECS | AF6000000 |
| FLUKA BRAND F CODES | 19 |
| TSCA | Yes |
| HS Code | 29159080 |
| Hazard Class | 6.1 |
| Packing Group | II |
溴醋酸乙酯 - Reference Information
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Use | ethyl bromoacetate can be used as an intermediate in organic synthesis, medicine and pesticide. It can also be used to make military toxic gases. |
| production method | first, bromine is reacted with acetic acid and acetic anhydride in pyridine to prepare bromoacetic acid, ethyl bromoacetate is then formed by the reaction of bromoacetic acid with ethanol in the presence of sulfuric acid. |
| category | toxic substances |
| toxicity grade | high toxicity |
| Acute toxicity | Reference range intravenous-mouse LDL0: 15.8 mg/kg |
| flammability hazard characteristics | open flame, high heat, flammable oxidant; thermal decomposition or reaction with water to produce toxic bromide gas |
| storage and transportation characteristics | The warehouse is ventilated and dried at low temperature, separate storage of food additives |
| fire extinguishing agent | foam, carbon dioxide, sand, dry powder |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-09 02:00:04
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View History
溴醋酸乙酯
二(4-溴苯基)胺
对甲基苯乙酸甲酯
双(二甲胺基)磷酰氯
3-(3-甲基苯基)丙酸
2-巯基-4-氨基-7H-吡啶[2,3-D]嘧啶
1-苯基-3-(哌啶-1-基)丙烷-1-酮
1-叔丁氧羰基-4-甲氨基哌啶
Trimethylenebis(oxy)bismethane
2-[(2S,5S)-5-METHYL-3,6-DIOXOPIPERAZIN-2-YL]ACETAMIDE
二(4-溴苯基)胺
对甲基苯乙酸甲酯
双(二甲胺基)磷酰氯
3-(3-甲基苯基)丙酸
2-巯基-4-氨基-7H-吡啶[2,3-D]嘧啶
1-苯基-3-(哌啶-1-基)丙烷-1-酮
1-叔丁氧羰基-4-甲氨基哌啶
Trimethylenebis(oxy)bismethane
2-[(2S,5S)-5-METHYL-3,6-DIOXOPIPERAZIN-2-YL]ACETAMIDE