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胡椒酸

Piperonylic acid

CAS: 94-53-1

Molecular Formula: C8H6O4

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胡椒酸 - Names and Identifiers

Name Piperonylic acid
Synonyms PIPEROYLICACID
Piperonylic acid
RARECHEM AL BO 0210
3,4-METHYLENDIOXYBENZOIC ACID
3,4-Methylendioxy-benzoic acid
3,4-Methylenedioxybenzoic acid
3,4-(METHYLENEDIOXY)BENZOIC ACID
1,3-benzodioxole-5-carboxylic acid
1,3-BENZODIOXOLE-5-CARBOXYLIC ACID
3,4-(methylenedioxy)benzoic acid, piperonylic acid
Piperonylic acid, (3,4-Methylenedioxybenzoic acid)
1-3-Benzodioxole-5-carboxylic acid~3,4-(Methylenedioxy)benzoic acid
CAS 94-53-1
EINECS 202-342-8
InChI InChI=1/C8H6O4/c9-8(10)5-1-2-6-7(3-5)12-4-11-6/h1-3H,4H2,(H,9,10)

胡椒酸 - Physico-chemical Properties

Molecular FormulaC8H6O4
Molar Mass166.13
Density1.3579 (rough estimate)
Melting Point229-231 °C (lit.)
Boling Point254.32°C (rough estimate)
Flash Point139.6°C
Water Solubilityslightly soluble
Solubility Ethanol
Vapor Presure9.95E-05mmHg at 25°C
AppearanceWhite to white-like powder
ColorOff-white to beige
Merck14,7477
BRN150206
pKa4.35±0.20(Predicted)
Storage ConditionSealed in dry,Room Temperature
Refractive Index1.5090 (estimate)
MDLMFCD00005830
Physical and Chemical PropertiesWhite ribbed or needle-like crystals. Melting point 229 ℃. Slightly soluble in water, chloroform, cold ethanol, ether.

胡椒酸 - Risk and Safety

Risk CodesR22 - Harmful if swallowed
R37/38 - Irritating to respiratory system and skin.
R41 - Risk of serious damage to eyes
R36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S37/39 - Wear suitable gloves and eye/face protection
WGK Germany3
RTECSDF4912765
TSCAYes
HS Code29329970
Hazard NoteIrritant

胡椒酸 - Reference Information

NIST chemical information information provided by: webbook.nist.gov (external link)
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
biological activity piperonic acid is a natural molecule with methylenedioxy function, mimicking the structure of trans-cinnamic acid. Piperonylic acid is a selective inactivator of trans-cinnamate 4-hydroxylase.
Use organic synthesis intermediates.
production method piperonal aldehyde was oxidized with potassium permanganate at 70-80 °c to obtain piperonyl acid in a yield of 90-96%.
Last Update:2024-04-09 20:45:29
胡椒酸
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View History
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