12354-85-7
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer
CAS: 12354-85-7
Molecular Formula: C20H30Cl4Rh210*
12354-85-7 - Names and Identifiers
12354-85-7 - Physico-chemical Properties
| Molecular Formula | C20H30Cl4Rh210* |
| Molar Mass | 618.08 |
| Melting Point | >300°C |
| Water Solubility | Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether |
| Solubility | Chloroform (Sparingly), Methanol (Slightly) |
| Appearance | Orange to brown powder or crystal |
| Color | red |
| Storage Condition | Keep in dark place,Sealed in dry,Room Temperature |
| MDL | MFCD00061552 |
| Use | Oxidative olefination reactions C- C bond cleavage of secondary alcohols Ortho C- H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C- H B |
12354-85-7 - Risk and Safety
| Hazard Symbols | Xn - Harmful |
| Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S24/25 - Avoid contact with skin and eyes. |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 28439000 |
12354-85-7 - Reference Information
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| Use | Dichloro (pentamethylcyclopentadienyl) rhodium (III) dimer is a useful alkylation reagent and a catalyst that can insert α-diazo carbonyl into non-acidic primary sp3 CH bond. Dichloro (pentamethylcyclopentadienyl) rhodium (III) dimer is used as rhodium catalyst, synthetic material intermediate, etc. |
Last Update：2024-04-10 22:29:15
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