carboxin
carboxin
CAS: 5234-68-4
Molecular Formula: C12H13NO2S
carboxin - Names and Identifiers
| Name | carboxin |
| Synonyms | carboxin 5,6-dihydro-2-methyl-1,4-oxathiin-3-carboxanilide 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-carboxamide 2-methyl-N-phenyl-5,6-dihydro-1,4-oxathiine-3-carboxamide |
| CAS | 5234-68-4 |
| EINECS | 226-031-1 |
| InChI | InChI=1/C12H13NO2S/c1-9-11(16-8-7-15-9)12(14)13-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3,(H,13,14) |
carboxin - Physico-chemical Properties
| Molecular Formula | C12H13NO2S |
| Molar Mass | 235.3 |
| Density | 1.273g/cm3 |
| Melting Point | 91.1-91.7℃ |
| Boling Point | 420.6°C at 760 mmHg |
| Flash Point | 208.2°C |
| Water Solubility | 10.095 g/100 mL |
| Solubility | Insoluble in water, soluble in chloroform, acetone, benzene, ethanol and other organic solvents. |
| Vapor Presure | 2.79E-07mmHg at 25°C |
| Storage Condition | 2-8℃ |
| Refractive Index | 1.636 |
| MDL | MFCD00055403 |
| Physical and Chemical Properties | Density 1.45 melting point 91.1-91.7°C water-soluble 10.095g/100 mL |
| Use | Butenamide fungicides, with high absorption activity to basidiomycetes, mainly used to control crop rust and smut |
carboxin - Risk and Safety
| Risk Codes | R21/22 - Harmful in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. |
| Safety Description | S36 - Wear suitable protective clothing. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| UN IDs | UN2588 (Pesticide, solid, poisonous, n.o.s.); UN2902 (Pesticide, liquid, poisonous, n.o.s.) |
carboxin - Upstream Downstream Industry
carboxin - Uses and synthesis methods
| use | This product is a selective systemic fungicide. It uses methods such as seed dressing, stuffy seed and seed soaking to prevent wheat, oats, corn, sorghum, millet and other cereal smut. It can also be used for foliar spraying wine to prevent wheat, beans, pears and other rust diseases, cotton seedling diseases, verticillium wilt, blight, and wood preservatives. This product is effective for Rhizoctonia, especially suitable for seed treatment of cotton, peanuts, vegetables and sugar beets. It has a growth stimulating effect on crops. Wilmus is low-toxic to humans and animals, but it should not be in contact with eyes. Seeds treated with withering rust spirit are not edible or forage. |
| use | Butene amide fungicides have high systemic activity against basidiomycetes and are mainly used to control crop rust and smut |
| production method | α-chloroacetanilide is obtained by the reaction of acetanilide and sulfuryl chloride, and then condensed with mercaptoethanol. Raw material consumption quota: acetanilide 1090kg/t, sulfuryl chloride 880kg/t, mercaptoethanol (>95%)490kg/t, p-toluenesulfonic acid 30kg/t. |
Last Update：2024-04-10 22:29:15
carboxin - Nature
| biological activity | Carboxin (Carboxine) is a systemic fungicide and seed protector. |
| in vitro study |
Carboxin (Carboxine) is a systemic fungicide from the oxathiin class of agents. Carboxin demonstrates high specificity against the fungal class Basideomycetes , Deuteromycetes and Phycomycetes .
|
| chemical properties | white needle crystal. The melting point is 93-95 ℃(91.5-92.5 ℃), the solubility in water at 25 ℃ is 170ppm, acetone is 60%, benzene is 15%, dimethyl sulfoxide is 150%, and ethanol is 21% (all weight/weight). Except for strong acids and bases, it is relatively stable in general media. |
Last Update：2024-04-10 22:29:15
carboxin - Security information
| category | Pesticides |
| toxicity classification | Poisoning |
| acute toxicity | oral-rat LD50: 430 mg/kg; Oral-mouse LD50: 3200 mg/kg |
| flammability hazard characteristics | Combustion produces toxic nitrogen oxides and sulfur oxide gases |
| storage and transportation characteristics | The warehouse is ventilated and dry at low temperature; it is stored and transported separately from food raw materials |
| fire extinguishing agent | dry powder, foam, sand |
| occupational standards | STEL 1 mg/m3 |
Last Update：2024-04-10 22:29:15
carboxin - Security information
| dangerous goods mark | Xi,Xn |
| hazard category code | 21/22-36/37/38-20/21/22 |
| safety instructions | 36-26 |
| dangerous goods transport number | UN2588 (Pesticide, solid, poisonous, n.o.s.); UN2902 (Pesticide, liquid, poisonous, n.o.s.) |
| WGK Germany | 3 |
| RTECS number | RP4550000 |
| customs code | 29349990 |
| toxic substance data | 5234-68-4(Hazardous Substances Data) |
| Toxicity | LD50 in rats, mice (mg/kg): 430, 3200 orally (Dyadicheva) |
Last Update：2024-04-10 22:29:15
carboxin - Nature
| melting point | 91.1-91.7°C |
| boiling point | 420.6±45.0 °C(Predicted) |
| density | 1.45 |
| Vapor pressure | 2.5 x 10-5 Pa (25 °C) |
| refractive index | 1.6000 (estimate) |
| flash point | 100 °C |
| storage conditions | Sealed in dry,2-8°C |
| acidity coefficient (pKa) | 14.31±0.70(Predicted) |
| morphology | Crystals |
| color | White |
| water solubility | 10.095 g/100 mL |
| Merck | 13,1837 |
| BRN | 983249 |
| NIST chemical information | Carboxin(5234-68-4) |
| EPA chemical information | Carboxin (5234-68-4) |
Last Update：2024-04-09 19:04:55
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View History
Raw Materials for carboxin
Sulfuryl chloride
PARA TOLUENE
Acetoacetanilide
2-Mercaptoethanol
2-CHLORO-3-OXO-N-PHENYLBUTANAMIDE
Butanamide, 2-(acetyloxy)-3-oxo-N-phenyl-
PARA TOLUENE
Acetoacetanilide
2-Mercaptoethanol
2-CHLORO-3-OXO-N-PHENYLBUTANAMIDE
Butanamide, 2-(acetyloxy)-3-oxo-N-phenyl-
Downstream Products for carboxin