130004-33-0
Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride
CAS: 130004-33-0
Molecular Formula: C54H44Cl2P2Ru
130004-33-0 - Names and Identifiers
| Name | Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride |
| Synonyms | (S)-RuCl[(p-cymene(BINAP)Cl S-(-)-BINAP-CHLORO(P-CYMENE)RUTHENIUM CHLORIDE [bis(diphenylphosphino)binaphthyl]chloro(p-cumene)RuCl Bis(Diphenylphosphino)-1,1'-Binaphthalenechloro(P-Cymene)Ruthenium Chloride (R)-(+)-2,2'-[BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM (S)-(-)-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM )-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene] chloro(p-cymene)ruthenium chloride [(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE [(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE (S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (S)-(-)-2,2'-Bis(Diphenylphosphino)-1,1'-Binaphthalenechloro(P-Cymene)Ruthenium Chloride (R)-(+)-2,2'-Bis(Diphenylphosphino)-1,1'-Binaphthalenechloro(P-Cymene)Ruthenium Chloride Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride |
| CAS | 130004-33-0 |
| InChI | InChI=1/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2 |
130004-33-0 - Physico-chemical Properties
| Molecular Formula | C54H44Cl2P2Ru |
| Molar Mass | 926.86 |
| Melting Point | >100°C |
| Boling Point | 724.3℃ at 760 mmHg |
| Solubility | Chloroform (Sparingly) |
| Appearance | Brown crystalline powder |
| Color | orange |
| Storage Condition | 2-8°C |
| Sensitive | Air Sensitive |
130004-33-0 - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| WGK Germany | 3 |
| HS Code | 28439000 |
130004-33-0 - Introduction
Chloro [(S)-(-)-2,2 '-bis (diphenylphosphino)-1,1'-binaphthyl](P-cymene) ruthenium (II) chloride is an organic coordination compound. Its chemical formula is [C44H32Cl2N2P2Ru] and its molecular weight is 850.9g/mol.
The properties of the compound are as follows:
-Appearance: colorless crystal
-melting point: about 170-175 ℃
-Solubility: Soluble in some organic solvents (such as methanol and dichloromethane)
Chloro [(S)-(-)-2,2 '-bis (diphenylphosphino)-1,1'-binaphthyl](P-cymenin) ruthenium (II) chloride is often used as a raw material in chemical synthesis. It can be used as a ligand and catalyst, and play a catalytic role in some organic synthesis reactions. Specifically, chloro [(S)-(-)-2,2 '-bis (diphenylphosphino)-1,1'-binaphthyl] (p-cymene) ruthenium (II) chloride can be used in asymmetric hydrogenation, asymmetric hydrocoupling, asymmetric hydroborylation and the like to provide chiral selectivity.
The method for preparing chloro [(S)-(-)-2,2 '-bis (diphenylphosphine)-1,1'-binaphthyl](P-cymenin) ruthenium chloride (II) usually involves Multi-step reactions, including the synthesis of reaction intermediates and the synthesis of ruthenium compounds. Specific methods can refer to the relevant research literature and patents.
When using chloro [(S)-(-)-2,2 '-bis (diphenylphosphino)-1,1'-binaphthyl](P-cymenin) ruthenium (II) chloride, the following safety information should be noted:
-This compound may be harmful to humans and should be avoided by inhalation or contact with skin, eyes and mucous membranes. Appropriate personal protective equipment, such as lab gloves and protective glasses, should be worn.
-When preparing and handling the compound, it should be operated in a well-ventilated laboratory.
-The compound should be stored in a dry, cool place and isolated from oxygen and moisture.
The properties of the compound are as follows:
-Appearance: colorless crystal
-melting point: about 170-175 ℃
-Solubility: Soluble in some organic solvents (such as methanol and dichloromethane)
Chloro [(S)-(-)-2,2 '-bis (diphenylphosphino)-1,1'-binaphthyl](P-cymenin) ruthenium (II) chloride is often used as a raw material in chemical synthesis. It can be used as a ligand and catalyst, and play a catalytic role in some organic synthesis reactions. Specifically, chloro [(S)-(-)-2,2 '-bis (diphenylphosphino)-1,1'-binaphthyl] (p-cymene) ruthenium (II) chloride can be used in asymmetric hydrogenation, asymmetric hydrocoupling, asymmetric hydroborylation and the like to provide chiral selectivity.
The method for preparing chloro [(S)-(-)-2,2 '-bis (diphenylphosphine)-1,1'-binaphthyl](P-cymenin) ruthenium chloride (II) usually involves Multi-step reactions, including the synthesis of reaction intermediates and the synthesis of ruthenium compounds. Specific methods can refer to the relevant research literature and patents.
When using chloro [(S)-(-)-2,2 '-bis (diphenylphosphino)-1,1'-binaphthyl](P-cymenin) ruthenium (II) chloride, the following safety information should be noted:
-This compound may be harmful to humans and should be avoided by inhalation or contact with skin, eyes and mucous membranes. Appropriate personal protective equipment, such as lab gloves and protective glasses, should be worn.
-When preparing and handling the compound, it should be operated in a well-ventilated laboratory.
-The compound should be stored in a dry, cool place and isolated from oxygen and moisture.
Last Update：2024-04-10 22:29:15
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View History
130004-33-0
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alpha-Biotin-omega-carboxy succinimidyl ester poly(ethylene glycol) (PEG-MW 10.000 Dalton)
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4-Methyl-5-(2-acetoxyethyl)thiazole
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