16002-63-4
Phenylmagnesium Iodide
CAS: 16002-63-4
Molecular Formula: C6H5IMg
16002-63-4 - Names and Identifiers
| Name | Phenylmagnesium Iodide |
| Synonyms | Phenyliodomagnesium Magnesium, iodophenyl- Phenylmagnesium Iodide PHENYLMAGNESIUM IODIDE Phenylmagnesium iodide, 0.50 M in THF |
| CAS | 16002-63-4 |
| InChI | InChI=1/C6H5.HI.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1/rC6H5IMg/c7-8-6-4-2-1-3-5-6/h1-5H |
16002-63-4 - Physico-chemical Properties
| Molecular Formula | C6H5IMg |
| Molar Mass | 228.31 |
| Storage Condition | Room Temprature |
16002-63-4 - Risk and Safety
| UN IDs | UN 2924 3/8/PG I |
| Hazard Class | 3/8 |
| Packing Group | I |
16002-63-4 - Introduction
Phenylmagnesium Iodide is an organometallic compound with the chemical formula C6H5MgI. It is a white crystalline solid and can be dissolved in organic solvents such as ether and benzene.
Phenylmagnesium Iodide is often used as an important reagent in organic synthesis. It can react with alkyl halides to generate the corresponding alkyl magnesium iodide, which in turn can be used for addition reactions, carbonylation reactions, etc. with other compounds. It can also react with haloalkenes to form the corresponding alkenyl magnesium iodides, which are used in the synthesis of alkene compounds.
The method for preparing Phenylmagnesium Iodide is generally to react phenyl bromide or phenyl chloride with magnesium powder first, then add potassium Iodide or sodium Iodide to react to generate Phenylmagnesium Iodide. The reaction process is usually carried out under the protection of inert gas to ensure that the reaction system is isolated from air.
Regarding safety information, Phenylmagnesium Iodide is irritating and has an irritating effect on the eyes, skin and respiratory tract. Wear personal protective equipment such as safety glasses, gloves and masks when handling. Take care to avoid inhaling dust or splashing substances into the eyes and avoid contact with the skin. During use or storage, it needs to be isolated from oxygen or moisture to prevent flammability or dangerous reactions.
Phenylmagnesium Iodide is often used as an important reagent in organic synthesis. It can react with alkyl halides to generate the corresponding alkyl magnesium iodide, which in turn can be used for addition reactions, carbonylation reactions, etc. with other compounds. It can also react with haloalkenes to form the corresponding alkenyl magnesium iodides, which are used in the synthesis of alkene compounds.
The method for preparing Phenylmagnesium Iodide is generally to react phenyl bromide or phenyl chloride with magnesium powder first, then add potassium Iodide or sodium Iodide to react to generate Phenylmagnesium Iodide. The reaction process is usually carried out under the protection of inert gas to ensure that the reaction system is isolated from air.
Regarding safety information, Phenylmagnesium Iodide is irritating and has an irritating effect on the eyes, skin and respiratory tract. Wear personal protective equipment such as safety glasses, gloves and masks when handling. Take care to avoid inhaling dust or splashing substances into the eyes and avoid contact with the skin. During use or storage, it needs to be isolated from oxygen or moisture to prevent flammability or dangerous reactions.
Last Update：2024-04-10 22:29:15
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