2426-08-6
Butyl glycidyl ether
CAS: 2426-08-6
Molecular Formula: C7H14O2
2426-08-6 - Names and Identifiers
| Name | Butyl glycidyl ether |
| Synonyms | NBGE Butoxymethyloxirane Glycidol butyl ether Butyl glycidyl ether Butyl gylcidyl ether. 2-(butoxymethyl)oxirane 3-Butoxy-1,2-epoxypropane 1-butoxy-2,3-epoxy-propan Butyl 2,3-epoxypropyl ether (2R)-2-(butoxymethyl)oxirane n-Butyl glycidyl ether (BGE) 2,3-Epoxypropylbutylbutylether Butyl 2,3-epoxypropyl ether~Glycidol butyl ether |
| CAS | 2426-08-6 |
| EINECS | 219-376-4 |
| InChI | InChI=1/C7H14O2/c1-2-3-4-8-5-7-6-9-7/h7H,2-6H2,1H3/t7-/m0/s1 |
2426-08-6 - Physico-chemical Properties
| Molecular Formula | C7H14O2 |
| Molar Mass | 130.18 |
| Density | 0.91g/mLat 25°C(lit.) |
| Melting Point | 59 °C |
| Boling Point | 164-166°C(lit.) |
| Flash Point | 132°F |
| Water Solubility | 2 g/100 mL |
| Solubility | 20g/l |
| Vapor Presure | 5 hPa (20 °C) |
| Appearance | Yellow liquid |
| Color | Clear colorless |
| Exposure Limit | ACGIH: TWA 3 ppm (Skin)OSHA: TWA 50 ppm(270 mg/m3)NIOSH: IDLH 250 ppm; Ceiling 5.6 ppm(30 mg/m3) |
| BRN | 103668 |
| Storage Condition | Store below +30°C. |
| Stability | Stable. May form explosive peroxides on contact with air. Store under inert gas. |
| Sensitive | Moisture Sensitive |
| Refractive Index | n20/D 1.418(lit.) |
| MDL | MFCD00005145 |
| Physical and Chemical Properties | Density 0.912 boiling point 164-166°C refractive index 1.418 flash point 132 °F water-soluble 2g/100 mL |
2426-08-6 - Risk and Safety
| Risk Codes | R10 - Flammable R20/22 - Harmful by inhalation and if swallowed. R37 - Irritating to the respiratory system R40 - Limited evidence of a carcinogenic effect R43 - May cause sensitization by skin contact R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R68 - Possible risk of irreversible effects R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R45 - May cause cancer R36/37/38 - Irritating to eyes, respiratory system and skin. R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. |
| Safety Description | S24/25 - Avoid contact with skin and eyes. S36/37 - Wear suitable protective clothing and gloves. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S53 - Avoid exposure - obtain special instructions before use. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| UN IDs | UN 3271 3/PG 3 |
| WGK Germany | 2 |
| RTECS | TX4200000 |
| FLUKA BRAND F CODES | 9-21 |
| TSCA | Yes |
| HS Code | 29109000 |
| Hazard Class | 3 |
| Packing Group | III |
| Toxicity | LD50 orally in Rabbit: 1660 mg/kg LD50 dermal Rabbit 2520 mg/kg |
2426-08-6 - Reference Information
Open Data Unverified Data
| LogP | 0.63 at 25℃ |
| (IARC) carcinogen classification | 2B (Vol. 125) |
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| overview | n-butyl glycidyl ether is a colorless liquid with a slightly irritating smell. it is used as a viscosity reducer and chemical intermediate for epoxy resin and as a solvent stabilizer for chlorination. |
| Preparation | n-butyl glycidyl ether was synthesized with n-butanol and epichlorohydrin as raw materials, boron trifluoride ether complex as catalyst, and sodium hydroxide as the closed loop agent for the cyclic reaction. |
| use | epoxy resin reactive diluent has toughening effect, and can also be used as stabilizer and plasticizer of polyvinyl chloride this product can be used as reactive diluent of bisphenol a epoxy resin. Small toxicity, easy to use. And can improve the properties of some resins after hardening, such as impact strength. used as a reactive diluent mainly used for the synthesis of isobutyric acid ester products, with more than 100 varieties. The main ester products are methyl isobutyrate, propyl ester, isoamyl |
| Production method | From butanol and epichlorohydrin as raw materials, it is synthesized through a two-step reaction. The specific technological process is as follows: 267kg of butanol and 32kg of concentrated sulfuric acid with a concentration of 96% are added to the reaction kettle, stirred, raised to 55 ℃, 324kg of epichlorohydrin is added dropwise, the temperature is controlled at 55-60 ℃ for about 4 hours, and the temperature is kept at 60-65 ℃ for 2 hours. Then, cool to 45 ℃, slowly add the mixed solution of tin tetrachloride and butanol (5kg tin tetrachloride dissolved in 5kg butanol), and then keep the temperature at 60-65 ℃ for 4 hours. After the reaction, decompressed distillation recovers unreacted epichlorohydrin and butanol until the temperature reaches 85-95 ℃ and the vacuum degree is 93.1kPa without epichlorohydrin and butanol. The epichlorohydrin butyl ether was obtained. The above reaction materials are cooled to 30-35 ℃, 432kg of sodium hydroxide with a concentration of 30% is added dropwise for about 4 hours, then the temperature is raised to 35-40 ℃ and the temperature is kept for 3 hours, then pure benzene is added under stirring, the temperature is raised until brine and alkaline water are released, and then the pH is about 6.5-7. Release the washing water, raise the temperature and remove benzene at normal pressure until the temperature of the feed liquid reaches 140 ℃, and then cool the discharge. The total yield of the two steps is about 95% based on butanol. |
| category | flammable liquid |
| toxicity classification | poisoning |
| acute toxicity | oral-rat LD50: 2050 mg/kg; Oral-mouse LD50: 1520 mg/kg |
| stimulation data | skin-rabbit 454 mg/3 days mild; Eye-rabbit 0.75 mg/24 hours severe |
| Explosive hazard characteristics | Flash point above; Blending with air can explode |
| flammability hazard characteristics | flammable; thermal decomposition discharges spicy and irritating smoke |
| storage and transportation characteristics | warehouse ventilation and low temperature drying; separate from oxidant |
| fire extinguishing agent | water, dry powder, carbon dioxide, foam |
| occupational standard | TWA 135 mg/m3; STEL 200 mg/m3 |
| spontaneous combustion temperature | 215°C |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
| immediate life-threatening and health concentration | 250 ppm |
Last Update：2024-04-09 19:43:38
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