Molecular Formula | C8H10Cl2O2 |
Molar Mass | 209.071 |
Density | 1.433±0.06 g/cm3(Predicted) |
Boling Point | 290.6±30.0 °C(Predicted) |
Storage Condition | 2-8℃ |
Physical and Chemical Properties | Chemical quality This product is white crystal, m.p.90 ℃, insoluble in water, soluble in benzene, toluene, chloroform and other organic solvents. |
Use | Uses 1R-cis-dichloropolyamic acid is an intermediate of cis-permethrin and deltamethrin. |
Raw Materials | p-Toluidine cis-DL-3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid 1,3-Propanediol 4-Methylphenethylamine |
acidity coefficient (pKa) | 4.66±0.42(Predicted) |
EPA chemical information | Cyclopropanecarboxylic acid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-, (1R,3R)- (55667-40-8) |
The preparation method is to use (±) cis-dichlorochrysanthemum acid for resolution, and the resolution agent can use L-( )-Su-type-N,N-dimethyl p-nitrophenyl -1,3-Propanediol, 1-phenyl -2-p-methyl phenylethylamine, (-)-1-p-methyl phenethylamine, etc.
Place (±) cis-dichlorochrysanthemum acid and (-)-1-p-methylaniline in a round bottom flask, slowly heat to dissolve, and then cool the solution to room temperature to obtain () cis-dichlorochrysanthemum acid and The salt formed by the splitting agent, then it was extracted with ether and desolted to obtain 1R-cis-dichlorochrysanthemum acid with optical purity of 98.1%. If (-)-1-phenyl-2-p-methylphenylethylamine is used as the resolution agent, the optical purity of 1R-cis-dichlorochrysanthemum acid obtained is low.